接触氧化法除铁的滤料选择

本文从锰砂滤料处理含铁废水中面对的问题入手，找出催化主要作用者“铁质活性滤膜”，引申而采用其它可培养出该膜之滤料，使在处理效果达到情况下，滤料来源更广泛、更经济、更方便。     

溶解氧和温度对地下水除铁、锰效果的影响

研究锰砂滤层去除铁、锰过程中温度、溶解氧两个因素对去除效果的影响，为生物法除铁、锰的实际运行提供了参考依据。从经济性和微生物角度考虑，原水DO维持在3mg／L左右即可满足运行要求，采用跌水曝气的方式去除效果优于管道混合器。当铁锰共存时最适宜的处理环境温度为20℃。     

煤矿矿井水除铁技术

本文从煤矿矿井水中铁的来发布和存在形式入手，剖析了接触氧化过滤除铁的机理，从曝气充氧方式，滤料选择，反冲洗条件及其参数确定等方面介绍含铁矿井水接触氧化除铁的技术关键，并结合工程实际证明该工艺技术的可行性和可靠性。     

酸性矿井水中和沉淀法除铁优化

针对山西某煤矿高矿化度、高铁酸性矿井水除铁效果差、出水容易返色等问题,采用NaOH中和调pH、曝气及化学氧化等处理工艺进行酸性矿井水中和沉淀法除铁优化实验研究。结果表明,采用NaOH中和沉淀法除铁时,投加中和剂使出水pH达6.7以上时,出水中铁含量低于10 mg/L,满足排放要求。对于本实验废水NaOH所需投加量为2.8 g/L,铁的去除率可达到99.75%;以H2O2对原水进行氧化处理,可迅速将Fe(Ⅱ)氧化成Fe(Ⅲ),其用量与原水中Fe(Ⅱ)的含量成正比。当其用量为1.6 mL/L时,可将原水中的Fe(Ⅱ)完全转化为Fe(Ⅲ),投加中和剂使出水pH达到4.5以上时,能使出水中铁含量满足排放要求。对于实验废水所需的NaOH投加量为2.0 g/L,比直接中和沉淀所需的NaOH用量要节省28.6%。曝气处理对原水中Fe(Ⅱ)的氧化效果不明显。     

Removal of phosphate by Fe-coordinated amino-functionalized 3D mesoporous silicates hybrid materials

Phosphate removal from aqueous waste streams is an important approach to control the eutrophication downstream bodies of water. A Fe(III) coordinated amino-functionalized silicate adsorbent for phosphate adsorption was synthesized by a post-grafting and metal cation incorporation process. The surface structure of the adsorbent was characterized by X-ray di raction, N2 adsoropion/desoprotion technique, and Fourier transform infrared spectroscopy. The experimental results showed that the adsorption equilibrium data were well fitted to the Langmuir equation. The maximum adsorption capacity of the modified silicate material was 51.8 mg/g. The kinetic data from the adsorption of phosphate were fitted to pseudo second-order model. The phosphate adsorption was highly pH dependent and the relatively high removal of phosphate fell within the pH range 3.0–6.0. The coexistence of other anions in solutions has an adverse e ect on phosphate adsorption; a decrease in adsorption capacity followed the order of exogenous anions: F?? > SO2?? 4 > NO??3 > Cl??. In addition, the adsorbed phosphate could be desorbed by NaOH solutions. This silicate adsorbent with a large adsorption capacity and relatively high selectivity could be utilized for the removal of phosphate from aqueous waste streams or in aquatic environment.     

EDTA直接滴定测定镍

参考磷酸在345~356℃时有强腐蚀性的特点,采有硫磷混合酸消解矿样,能使样品消解完全。本方法经加标校核证明,检测结果重现性好,准确度高。     

浅谈地下水净化厂除铁除锰试验及应用

通过对齐齐哈尔市自来水公司铁锋水厂除铁、锰工艺的分析,得出曝气接触氧化除铁、锰是一种好方法.     

黄钠铁矾除铁废渣的回收利用

黄钠(钾)铁矾除铁是六十年代澳大利亚雷斯顿电锌厂经多年试验研究发展起来的一种有效的除铁新技术,它是利用Na~+、K~+和NH_4~+离子与有价金属硫酸盐溶液中的Fe~(3+)形成黄铁矾Na_2Fe_6(SO_3)_4(OH)_(12)、K_2Fe_6(SO_4)_4(OH)_(12)和(NH_4)_2Fe_6(SO_4)_4(OH)_(12)