‘Emulsion locks’ for the containment of hydrocarbons during surfactant flushing

Reversible double water in oil in water (W/O/W) emulsions were developed to contain subsurface hydrocarbon spills during their remediation using surfactant flushing. Double emulsions were prepared by emulsifying CaCl₂ solutions in canola oil, and subsequently by emulsifying the W/O emulsions in aqueous sodium alginate solutions. The formation of double emulsions was confirmed with confocal and optical microscopy. The double emulsions reversed and gelled when mixed with the surfactants sodium dodecyl sulfate (SDS) and cocamidopropyl betaine (CPB). Gels can act as ‘emulsion locks’ to prevent spreading of the hydrocarbon plume from the areas treated with surfactant flushing, as shown in sand column tests. Shear rheology was used to quantify the viscoelastic moduli increase (gelation) upon mixing the double emulsion with SDS and CPB. SDS was more effective than CPB in gelling the double emulsions. CPB and SDS could adsorb at the interface between water and model hydrocarbons (toluene and motor oil), lowering the interfacial tension and rigidifying the interface (as shown with a Langmuir trough). Bottle tests and optical microscopy showed that SDS and CPB produced W/O and O/W emulsions, with either toluene or motor oil and water. The emulsification of motor oil and toluene in water with SDS and CPB facilitated their flow through sand columns and their recovery. Toluene recovery from sand columns was quantitated using Gas-Chromatography Mass-Spectroscopy (GC-MS). The data show that SDS and CPB can be used both for surfactant flushing and to trigger the gelation of ‘emulsion locks’. Ethanol also gelled the emulsions at 100 mL/L.     

Comparative analysis of anaerobically digested wastes flow properties

The flow curve of anaerobically digested wastes from different origins was determined through rheological measurements. Regardless of their origin, samples can be divided into two families: simple non-Newtonian liquids well modelled by basic power law below 10%DC and viscoelastic liquids with a yield stress, well modelled by a Herschel–Bulkley model above. In all the cases, the rheological behaviour is driven by both the organic content and the volatile fraction (organic content/solid content), indicating that anaerobic digestion tends to smooth the rheological characteristics of organic wastes, whichever their origins.     

基于安全流变理论的交通系统事故过程分析

运用事物的安全流变规律分析系统的运行过程 ,指出系统的运行过程符合安全流变规律。通过对交通系统中的不安全因素扰动的分析 ,揭示了交通系统的安全流变特征 ;对传统的事故定义进行了拓展 ,将事故隐患纳入了事故的发展过程 ;提出了交通系统事故安全流变分析方法 ;最后通过一个具体的案例分析了系统事故的安全流变过程。     

安全流变理论及其在煤矿事故中的应用

提出了“安全流变理论”,分析了事物“安全流变”的基本特征和理论基础 ,描述了煤矿事故的安全流变特性 ,同时指出煤矿事故的发生和发展可以用“安全流变理论”进行解释 ,进而说明“安全流变理论”是符合事物发展变化规律的。     

安全科学基本理论规律研究

通过对事物发展过程中的安全与危险的矛盾运动过程分析,抽象出一些基本概念和事故从孕育到发生发展及结束和后效阶段的基本特征,并对部分事例进行了分析。提出了安全科学的统一规律——安全流变与突变论,并初步建立了安全流变论的数学模型     

Evaluation of ionic fluids as lubricants in manufacturing

Ionic fluids are liquid salts that have been investigated for a number of applications, including catalysis, their use as solvents and electrically conducting fluids. Chemically, they consist of ionically bonded species, and depending on the cation and anion, can be extremely valuable in the chemical processing industry. Another characteristic that makes them useful is a high viscosity and good lubrication properties. This paper examines a number of ionic fluids, and determines their suitability as lubricants. This involves determining rheological properties, including viscosity and high-pressure viscosity, generally using a Barus law. In addition, their traction behavior is measured to evaluate their lubricating properties. Since metalworking fluids (and lubricants in general) are used in non-isothermal situations, the thermal conductivity of these fluids have also been measured.     

Fly and bottom ashes from biomass combustion as cement replacing components in mortars production: Rheological behaviour of the pastes and materials compression strength

In the present research mortar pastes obtained by replacing a commercial cement with the equivalent mass of 5, 10, 20 and 30 wt.% of fly ash or bottom ash from fir chips combustion, were prepared and rheologically characterized. It was observed that the presence of ash modifies their rheological behaviour with respect to the reference blend due to the presence, in the ashes, of KCl and K₂SO₄ which cause precipitation of gypsum and portlandite during the first hydration stages of the pastes. Hydrated materials containing 5 wt.% of ash display compression strength and absorption at 28 d of same magnitude as the reference composition; conversely, progressive increase of ash cause a continuous decline of materials performances. Conversely, samples tested after 180 d display a marked decline of compression strength, as a consequence of potassium elution and consequent alkali-silica reaction against materials under curing.