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IntroductionPolyaluminiumchloride(PAC) ,akindofinorganicpolymerflocculant,iswidelyusedinwaterandwastewatertreatment.InordertoincreasethecoagulationeffectofPACandimprovethequalityofPACproduct,itisnecessarytoraisethedegreeofpolymerizationofPAC .Generally ,t… 相似文献
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Al-Ferron逐时络合比色法研究PACS中铝的水解聚合形态 总被引:13,自引:0,他引:13
制备了碱化度(B)及不同Al~(3+)/SO_4~(2-)摩尔比的系列PACS,用Al-Ferron逐时络合比色法研究了铝的形态分布,考察了碱化度(B)、Al~(3+)/SO_4~(2-)摩尔比、稀释作用及pH值对铝的形态分布的影响.实验结果表明,Al~(3+)/SO_4~(2-)摩尔比及溶液的pH值对铝的形态分布有较大的影响,稀释作用对铝的形态分布影响较小.Al~(3+)/SO_4~(2-)摩尔比愈小,pH值愈高,铝的水解聚合大分子及胶体粒子所占的比例就愈大. 相似文献
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PACS絮凝除油效果及其数学模型研究 总被引:2,自引:0,他引:2
PACS作为一种处理油田含油污水的高效絮凝剂,目前已在油田含油污水的净化中得到了广泛的应用。本文就不同的PACS投加量对不同含油量的油田含油污水的除油效果,进行了实验研究,得到了一系列实验结果,并根据所得结果通过模型识别和多参数最优估计方法,建立了除油率与PACS的投加量和含油污水含油量之间的非线性数学模型,得到了令人满意的结果。 相似文献
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PACS的结构特征及絮凝性能研究 总被引:11,自引:0,他引:11
制备了碱化度及Al^3+/SO^2-4摩尔比不同的系列PACS,分别进行常压(干燥温度105℃)及真空干燥(真空度为-0.098MPa、干燥温度65℃)制备固体产品。用红外光谱及X-射线衍射谱研究了碱化度、Al^3+/SO^2-4摩尔比、干燥温度对PACS的结构影响,比较了干燥温度不同对PACS固体样品的溶解度及絮凝效果的影响,借助于显微电泳测定技术研究不同碱化度及不同Al^3+/SO^2-4摩尔 相似文献
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Distribution of aluminum species and the characteristics of structure of poly-aluminum-chloride-sulfate(PACS) 总被引:1,自引:0,他引:1
IntroductionPolyaluminumchloride (PAC) ,whichwasdevelopedinthe 1960’sinJapan ,hascometobeusedextensivelyin placeofaluminumsulfateinwaterandwastewatertreatmentbecauseofitsabilitytoachieveadequateaggregationevenatlowtemperaturesandtoformflocsrelativelyrapidl… 相似文献
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Polyaluminium chlorides with sulfate ion(PACS) were prepared by using AlCl3· 6H2O, Al(SO4 )3· 18H2O and Na2CO3 as raw materials. The effects of basicity (r), Al3 +/SO42- molar ratio and aging time on the morphology of PACS were observed by transmission electrical microscope. The influence of aging time on charge neutralization and coagulation effect of PACS was studied.The effects of basicity (r), Al3+/SO42- molar ratio and aging time on the electrical conductivity of PACS solution were also investigated. The experimental results show that the degree of polymerization of polyaluminium chloride(PAC) increases when SO42-ion is added. The higher the basicity(r) and the longer the aging time, the larger the size of polymer PACS. The ability of PACS neutralizing the charge on Kaolinite decreases with the increase of aging time. The electrical conductivity of PACS solution (the concentration of Al3+ ion is 0.18 mol/L) with different aging time is the function of the basicity and Al3 +/SO42- molar ratios and has its maximum at r = 0.5 and Al3+/SO42- = 12. 相似文献
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