混凝沉淀-酸化水解-接触氧化工艺处理聚苯乙烯生产废水

采用混凝沉淀酸化水解生物接触氧化工艺处理聚苯乙烯生产废水,通过治理工程实际运行,结果表明:当废水CODCr平均浓度为1160mg/L时,CODCr去除率为882%,出水水质稳定,能达到设计要求。     

用GC/MS分析火灾后苯板产生固体废物中的有机物

采用GC/MS方法对某苯板厂火灾后产生的固体废弃物进行检测分析.结果表明,在苯板火灾后产生的固体废弃物中检测出61种化合物,其中被美国EPA列入优先污染物的苯系物、萘和蒽等占总有机物12.2％.     

Degradation of PVC Containing Mixtures in the Presence of HCl Fixators

Degradation of a model polymer mixture (PVC/PS/PE) and a waste polymer mixture in the presence of HCl fixators (Red Mud, precipitated CaCO₃ and dolamite) was studied using thermal gravimetric analysis (TGA) and a cycled-spheres-reactor. The experiments in cycled-spheres reactor model were performed by stepwise pyrolysis. Liquid products and HCl from each step were collected separately. For the model polymer mixture, the precipitated CaCO₃ showed the best effect on the fixation of evolved HCl and the reduction of chlorine content in the liquid products whereas RM yielded the best result for the waste polymer mixture. In addition, using HCl fixator also affected the degradation of both types of polymer mixture, leading to the formation of more gaseous and less residue.     

聚苯乙烯泡沫芯材的燃烧特性及其在火灾事故原因调查中的应用

利用热解分析、热电偶束和ISO9705房屋/墙角等实验装置测试了彩钢板中聚苯乙烯泡沫(EPS)芯材的热解特性和水平方向的温度分布及整体板材的燃烧特性,结合某乳液公司冷库火灾事故原因调查,分析评价了EPS泡沫夹芯板的潜在和实际火灾危险性,证实了EPS芯材内部的燃烧和热传播为火灾蔓延的主要原因.     

聚苯乙烯基离子交换纤维去除铅离子的应用研究

聚苯乙烯其离子交换纤维是一种理想的离子交换材料。它的特殊的物理形态决定它对一些有害气体如铅烟、颗粒铅等具有很好的净化作用，铅烟净化效率可达８０％；对水溶液中毒性铅离子去除率可达８６％。该纤维可做为治理毒性铅离子的材料。     

Cracking styrene derivative polymers in decalin solvent with metal-supported carbon catalysts

The cracking of styrene derivative polymers dissolved in decalin was conducted with metal-supported carbon catalysts under an inert gas atmosphere to recover monosubstituted styrene or monosubstituted ethylbenzene in higher yields than is obtained by pyrolysis, and to elucidate the detailed reaction mechanisms in the solvent. Poly-(4-methylstyrene), poly-(4-t-butylstyrene), poly-(α-methylstyrene), and polystyrene were used. In decalin without a catalyst, each polymer was decomposed into the monomer, dimer, and trimer derived from the corresponding polymer except for poly-(α-methylstyrene), which was decomposed into the monomer and styrene. By using metal-supported carbon, the olefinic compounds derived from the corresponding polymer were thoroughly hydrogenated to the saturated form in a nitrogen atmosphere by a hydrogen transfer reaction from decalin, which was simultaneously dehydrogenated to tetralin and naphthalene with the evolution of hydrogen gas. In comparison with metal species, Pd- and Ru-supported carbon catalysts maintained the hydrogenation activity for a longer time and with a lower evolution of hydrogen than Pt or Rh. The dehydrogenation of decalin was mainly observed not on the metal surfaces, but on the carbon surfaces over Pd-supported carbon. Stabilization of the monomers will be able to suppress the coking which occurs with repolymerization in long running process. Received: July 19, 2000 / Accepted: March 16, 2001     

Recycling extruded polystyrene by dissolution with suitable solvents

The amount of extruded polystyrene (XPS) waste has increased in recent years due to the increase of its use in the thermal insulation of buildings, transport vehicles, and refrigerators, among others. Dissolution with suitable solvents to achieve a volume reduction of more than 100 times without degradation of polymer chains is one of the cheapest and most efficient methods of recycling XPS. Several environmentally friendly solvents have been tested as dissolution agents for XPS volume reduction; the action of these solvents does not produce any degradation of polymer chains. The solubility of the polymer in such solvents at different temperatures was investigated. The solvent can be easily recycled by distillation, obtaining a high-quality recycled polymer. Chemical Feedstock Recycling & Other Innovative Recycling Techniques 6     

Converting waste polystyrene into a polymer flocculant for wastewater treatment

We have succeeded in converting waste polystyrene from electrical appliances into a polymer flocculant for treating some kinds of wastewater after chemical modification. Waste polystyrene, such as polystyrene foam and additive-containing TV cabinets, was converted into a water-soluble polymer, polystyrene sulfate (PSS), and PSS of various degrees of aqueous viscosity was obtained by introducing sulfone bridges during sulfonation. We examined the relationship between the degree of flocculation of wastewater and the aqueous viscosity of the PSS, and found that PSS with medium viscosity is most suitable for flocculating inorganic wastewater from a factory, and PSS with high viscosity is most suitable for dewatering organic domestic wastewater. We report how PSS containing sulfone bridges works as a polymer flocculant for treating wastewater. Received: July 19, 2000 / Accepted: September 21, 2000     

二硫化铁(FeS2)纳米颗粒对聚苯乙烯(PS)热稳定性和燃烧性能的影响

采用熔融共混法制备聚苯乙烯(PS)/二硫化铁(FeS2)纳米复合材料研究FeS2对PS热稳定性和燃烧性能的影响。扫描电镜(SEM)结果表明FeS2能够很好地分散在PS基体中。热重分析(TGA)的数据显示,FeS2可以显著地提高残余炭量。锥形量热仪(CONE)结果表明,FeS2可以改变PS的分解,从而在复合材料的表面上形成炭层,导致燃烧和烟气方面的参数有效降低,如热释放速率(HRR)、总热释放(THR)、烟释放率(SPR)、烟释放总量(TSR)、平均质量损失速率(AMLR)和平均烟消光面积(ASEA)等。此外,极限氧指数也得到了提高。拉曼(LRS)的结果证实了残余炭中有石墨碳的存在,热降解过程中石墨碳的形成有利于对热扩散的抑制,从而改善了PS的热稳定和燃烧性能。     

利用废弃聚苯乙烯泡沫塑料生产油性腻子的研究

为了减少白色污染物聚苯乙烯泡沫塑料废弃物对环境的污染,以生活及工业废弃物聚苯乙烯泡沫塑料与活性白土为主要原料,加入适量乙酸乙酯,搅拌均匀即得一种油性腻子。该产品的性能与同类腻子相似,其制造成本低,取料容易,适用于镶嵌玻璃,也可作其它填平凹坑,缝隙。