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微生物法液相氧化SO2 总被引:6,自引:0,他引:6
通过对酸性水溶液、含Fe3+水溶液、含Fe2+水溶液、细菌菌液和细菌培养基水溶液脱除二氧化硫的实验,探讨了微生物液相氧化二氧化硫的途径.以液相中SO42-浓度考察了Fe3+浓度、Fe2+浓度、进口SO2浓度以及温度对脱硫成酸的影响.微生物脱硫有2种机制:一是直接氧化作用,即氧化亚铁硫杆菌(Thiobacillus ferrooxidans)将S(IV)氧化成S(VI);二是间接催化氧化,氧化亚铁硫杆菌在酸性条件下具有快速氧化Fe2+成Fe3+,增强Fe3+对SO2的液相催化氧化能力,研究表明微生物脱硫以间接催化氧化为主.在浓度0~1.2g/L之间,Fe3+和Fe2+浓度越高,脱硫效果越好,氧化亚铁硫杆菌表现出对Fe3+/Fe2+体系氧化SO2的强化效果.入口SO2浓度越高,细菌脱硫效率越低,但液相中SO42-浓度随进口SO2浓度增加变化不大.温度对微生物脱硫影响较大,最佳脱硫温度为30~40℃. 相似文献
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苯并噻吩脱硫菌株的筛选及脱硫活性研究 总被引:1,自引:0,他引:1
从孤岛油田油浸土样中筛选到1株能降解苯并噻吩(BT)的脱硫菌,经初步鉴定该菌为戈登氏菌属(Gordona sp.).实验证明:该菌能以类似于4S途径脱除BT及其衍生物中的硫,但是不能脱除二苯并噻吩(DBT)及其衍生物中的硫.GC-MS分析表明该途径的终产物为邻羟基苯乙醛或其异构体苯并呋喃.在以BT为唯一硫源的培养基中30℃培养48h,Gordona sp.C-6能降解0.15mmol/L的BT,终产物占发酵培养基中BT加入量的50%,其余BT在有氧培养过程中挥发.通过Matlab拟合曲线确定以邻羟基苯乙酸为标准品进行产物定量检测的方法. 相似文献
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Rhodococcus erythropolis USTB-03 is a promising bacterial strain for the biodesulfurization of dibenzothiophene (DBT) via a sulfurspecific pathway in which DBT is converted to 2-hydroxybiphenyl (2HBP) as an end product. The effects of nicotinamide and riboflavin on the sulfur specific activity (SA) of DBT biodesulfurization by R. erythropolis USTB-03 were investigated. Both nicotinamide and riboflavin were found to enhance the expression of SA, which was not previously reported. When R. erythropolis USTB-03 was grown on a medium containing nicotinamide of 10. 0 mmol or riboflavin of 50. 0 μnol, SA was raised from 68. 0 or so to more than 130 mmol 2HBP/(kg dry cells. h). When R. erythropolis USTB-03 was grown in the presence of both nicotinamide of 5. 0 mmol and riboflavin of 25. 0 μmol, SA was further increased to 159. 0 mmol 2HBP/(kg dry cells. h). It is suggested that the biological synthesis of reduced form of flavin mononucleotide (FMNH2), an essential coenzyme for the activities of biodesulfurization enzyme Dsz C and A, might be enhanced by nicotinamide and riboflavin, which was responsible for the increased SA of R. erythropolis USTB-03. 相似文献
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为了降低工业废气中的硫化氢去除工艺成本和运行费用,对三价铁盐吸收与氧化亚铁硫杆菌对Fe2+的生物氧化联合作用脱除H2S进行了研究。通过生物氧化塔中的固定化氧化亚铁硫杆菌细胞再生的Fe3+溶液,在H2S还原吸收塔中脱除H2S。通过单因素实验分别优化了生物氧化塔和H2S吸收塔的运行参数,在生物氧化塔曝气量为150 L/h,停留时间为11 h,吸收液中Fe3+浓度为0.121~0.143 mol/L,吸收液流量为0.3 L/h,进气量为100 L/h条件下,进气中H2S浓度分别为2.28和9.11 mg/L,系统连续运行至200 min时趋于相对稳定,当系统连续运行稳定时,H2S的脱除率可分别达到95%和91%,脱除效果显著。 相似文献
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Ashutosh Bahugun Madhuri K. Lily Ashok Munjal Ravindra N. Singh Koushalya Dangwal 《环境科学学报(英文版)》2011,23(6):975-982
A new bacterial strain DMT-7 capable of selectively desulfurizing dibenzothiophene (DBT) was isolated from diesel contaminated
soil. The DMT-7 was characterized and identified as Lysinibacillus sphaericus DMT-7 (NCBI GenBank Accession No. GQ496620)
using 16S rDNA gene sequence analysis. The desulfurized product of DBT, 2-hydroxybiphenyl (2HBP), was identified and
confirmed by high performance liquid chromatography analysis and gas chromatography-mass spectroscopy analysis respectively.
The desulfurization kinetics revealed that DMT-7 started desulfurization of DBT into 2HBP after the lag phase of 24 hr, exponentially
increasing the accumulation of 2HBP up to 15 days leading to approximately 60% desulfurization of the DBT. However, further growth
resulted into DBT degradation. The induced culture of DMT-7 showed shorter lag phase of 6 hr and early onset of stationary phase
within 10 days for desulfurization as compared to that of non-induced culture clearly indicating the inducibility of the desulfurization
pathway of DMT-7. In addition, Lysinibacillus sphaericus DMT-7 also possess the ability to utilize broad range of substrates as sole
source of sulfur such as benzothiophene, 3,4-benzo DBT, 4,6-dimethyl DBT, and 4,6-dibutyl DBT. Therefore, Lysinibacillus sphaericus
DMT-7 could serve as model system for efficient biodesulfurization of diesel and petrol. 相似文献
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