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采用石墨炉原子吸收法测定水中铊,对样品前处理的多个细节进行改进,使前处理过程耗时缩短,回收率提高。试验表明,方法在0μg/L ~50.0μg/L范围内线性良好,相关系数r为0.9995;检出限为2.0μg/L,取样量为500 mL,富集50倍时,方法检出限为0.04μg/L;实际水样测定结果的 RSD 为4.9%~8.4%;实际样品的加标回收率为94.0%~102%。 相似文献
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M.?Purenovi? J.?Perovi? A.?Boji?Email author T.?An?elkovi? D.?Boji? 《Environmental Chemistry Letters》2004,2(2):59-63
We studied the removal of cadmium and copper from industrial wastewaters by a microalloyed aluminium composite. The composite was highly efficient, resulting in water concentrations of cadmium and copper below the maximal allowed concentrations for drinking water. Moreover, our results show that the removal mechanism is mainly based on reduction and coprecipitation, since Cd and Cu were removed from the wastewater in reduced forms as metals and hydroxides.Selected article from the Regional Symposium on Chemistry and Environment, Krusevac, Serbia, June 2003, organised by Dr. Branimir Jovancicevic 相似文献
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研究提出了用磷酸钕(NdPO4)作为共沉淀捕集剂分离富集环境水样中的痕量Pb2 ,用火焰原子吸收光谱(FAAS)测定的方法.共沉淀受pH、NdCl3和H3PO4溶液用量的影响.结果显示,在溶液pH为3.2时,20 mL水样中加入5 mg/L NdCl3 2 mL、0.5 mol/L H3PO4 3 mL条件下,铅的加标回收率为96.6%~104.2%,方法的检测限为5.7×10-3 mg/L,水体中常见碱金属、碱土金属离子及阴离子在一定范围内不影响测定. 相似文献
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We studied soil and ground water samples from the tailings disposal site near Tuba City, AZ, located on Navajo sandstone, in terms of uranium adsorption and precipitation. The uranium concentration is up to 1 mg/l, 20 times the maximum concentration for ground water protection in the United States. The concentration of bicarbonate (HCO3−) in the ground water increased from ≤7×10−4 M, the background concentration, to 7×10−3 M. Negatively charged uranium carbonate complexes prevail at high carbonate concentrations and uranium is not adsorbed on the negatively charged mineral surfaces. Leaching experiments using contaminated and uncontaminated sandstone and 1 N HCl show that adsorption of uranium from the ground water is negligible. Batch adsorption experiments with the sandstone and ground water at 16°C, the in situ ground water temperature, show that uranium is not adsorbed, in agreement with the results of the leaching experiments. Adsorption of uranium at 16°C is observed when the contaminated ground water is diluted with carbonate-free water. The observed increase in pH from 6.7 to 7.3 after dilution is too small to affect adsorption of uranium on the sandstone. Storage of undiluted ground water to 24°C, the temperature in the laboratory, causes coprecipitation of uranium with aragonite and calcite. Our study provides knowledge of the on-site uranium chemistry that can be used to select the optimum ground water remediation strategy. We discuss our results in terms of ground water remediation strategies such as pump and treat, in situ bioremediation, steam injection, and natural flushing. 相似文献
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Europium(III) was coprecipitated with the clay mineral hectorite, a magnesian smectite, following a multi-step synthesis procedure. Different Eu(III) species associated with the proceeding synthetic hectorite were characterized by selectively exciting the 5D0-->7F0 transition at low temperature (T < 20 K). Fluorescence decay times indicated that Eu(III) ions may be incorporated in the octahedral layer of the brucite precursor as well as in the octahedral sheet of the clay mineral. The excitation spectra indicated that the substitution of the divalent Mg by the trivalent Eu induced local structural deformation. This investigation implements the molecular-level understanding of the f element structural incorporation into the octahedral layer of sheet silicates by coprecipitation with clay minerals from salt solutions at 100 degrees C. 相似文献
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A method for the preconcentration of the total chromium based on coprecipitation with cerium (IV) hydroxide is proposed for
determination of chromium by flame atomic absorption spectrometry. Different factors including carrier element amount, pH,
sample volume and matrix ion effects for the precipitation were examined. The detection limit of the total chromium (k = 3, N = 15) was 0.18 μg l−1. The presented method was applied for the determination of chromium in the wastewater samples from Kayseri and Nigde Organized
Industrial Region-Turkey and in drinking water from our laboratory, Kayseri with satisfactory results (relative standard deviations
below 8%, recoveries 95%). The analytical results obtained by the proposed method for certified copper sample was in good
agreement with the certified value. 相似文献
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Polyacrylic acid was hydrophobically modified with dodecylamine and used as a coagulant for coprecipitation of hydrophobic organic pollutants from water. The polymer coagulant induced effective aggregation of aluminum hydroxide having hydrophobic regions which are essential for the incorporation of hydrophobic organic pollutants. Recoveries of the organic pollutants increased with increasing the dodecylamine content, which indicated that the dodecylamine moiety played an important role in the formation of hydrophobic area on the precipitate. Different hydrophobic organic pollutants that had hardly been removed by the conventional coprecipitation were successfully collected by the proposed method. 相似文献
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