β修正罗丹明B光度法测定工业废水中银

对β修正光度法测定废水中痕量银进行了研究，该方法能消除反应液中过量显色剂干扰，提高分析灵敏度和准确度。测定结果表明，银加标回收率９３．０－１０６．０％，精密度ＲＳＤ２．３％，银量低测定浓度０．０２ｍｇ／Ｌ。该方法适合于印相，电镀等行业废水银分析。     

地质样品中27项元素的粉末压片法x射线荧光光谱测定

本文报导了用x射线荧光光谱法—次粉末压片制样同时测定Na. Mg. Al. Si.P. S. K. Ca. Ti. V. Cr. Mn. Fe. Co. Ni. Cu. Zn. Rb. Sr. Y. Zr. Nb. Ba. Hf. Pb. Th. U等27项元素的快速分析方法。从理论上提出了新的基体效应学校正模式,首次引入了非荧光分析的物质(筒称NFAM)的新概念;并计算了理论α系数,使理论α系数在粉末压片法x射线荧光分析中获得了应用。本方法测定的对象可以是岩石,土壤和水系沉积物等地质样品。     

修正SO2被动式采样器的感度

二氧化硫被动式采样器的采样感度受环境中湿度和硫酸盐等的影响，感度经修正后用于环境监测，其结果与紫外荧光法的相对误差小于１０％。     

Simple relationships between the ionization energies of one-, two- and three-electron ions of consecutive elements

The ionization energy of one-electron ions can be calculated from a well-known equation that is based on quantum mechanics and on the Bohr model, but no theoretically justified equation is available for the calculation of the ionization energies of multi-electron ions. I report here simple empirical relationships between the ionization energies of one-, two- and three-electron ions of elements whose atomic numbers are Z, Z + 1 and Z + 2. On the basis of these relationships, an equation was constructed for the calculation of the ionization energies of two- and three-electron ions (IE(2el)(Z) and IE(3el)(Z), respectively) as a function of Z only: [equation: see text] where N = the number of electrons, i.e. 2 or 3. For N = 3, this equation is only valid when Z > N, being inaccurate for the neutral Li atom. Graphs of the difference between calculated and experimental values of the ionization energies as a function of Z reveal inaccurate experimental results that are impossible to detect by inspection of the ionization energy itself. On the basis of the present results, more accurate values can be predicted for these ionization energies. A striking example is the inaccuracy of the traditional handbook value of IE(3el)(Fe).     

管道烟气静压测量方法探讨

通过对三种常用管道烟气静压测定法进行理论和试验分析,推荐一种实用的静压间接测定法,并对该法进行理论分析和试验验证。     

基于Models-3的自修正空气质量预报系统及其效果检验

本文介绍了一个以Models-3为基础的自动化空气质量数值预报系统,该系统通过Gambas、Yabasic和R语言等工具进行开发,集成WRF-SMOKE-CMAQ三个模式,可通过监测数据进行自动修正,完成空气质量业务数值预报,并将结果发布到Web服务器上进行呈现。该系统对硬件的要求较低,将部署于一台DELL Optiplex 9010工作站上,设置6km—2km双层嵌套,进行成都市空气质量数值预报。本文分析了成都市2014年1月1日至2014年12月31日的空气质量数值预报结果,评价系统对成都市NO_2、SO_2、PM_(10)、PM_(2.5)、O_3、CO以及空气质量指数(AQI)的预报效果。结果显示,系统对于成都市2014年空气质量变化情况趋势的预报效果较好,302天有效预报中,24小时直接预报的空气质量等级准确率为58.27%,AQI预报相关系数0.71,观测值自动修正预报对24小时空气质量预报具有明显改善效果,使其等级预报准确率达到64.9%,相关系数提高到0.89。     

庆阳市环境-经济耦合系统动态演变趋势分析:基于能值理论与计量经济分析模型

分析了1978～2007年庆阳市环境-经济系统的能值流量与能值效率的演变轨迹.并以环境负荷率(ELR)、能值废弃率(EWR)作为环境压力指标,运用协整检验、Granger因果检验和向量误差修正模型(VECM),通过分析人均GDP与环境压力指标变量之间在时序维度上的因果关系和相互影响程度,进一步阐述经济与环境系统的耦合关系及其动态特征.结果表明,庆阳市经济发展对不可更新资源的依赖度大,环境-经济系统的产出效率总体下降,但环境负荷不断上升.计量分析表明,经济增长与环境压力之间存在单向因果关系,且已形成"恶性循环圈",环境-经济耦合系统表现出不可持续的发展态势.     

The use of DPSIR framework to evaluate sustainability in coastal areas. Case study: Guanabara Bay basin,Rio de Janeiro,Brazil

The Guanabara Bay basin, SE Brazil, is shown as an experimental site to evaluate development and sustainability in coastal areas. We developed a Driver–Pressure–State–Impact–Response (DPSIR) framework in a practical context to integrate natural and socio-economic indicators. Sustainability reflects public policies towards the utilization of natural resources. Cost-benefit analysis (CBA) included in DPSIR evaluates losses and benefits resulting from such policies. CBA has some limitations due to the difficulty of valuating environmental goods and services. Instead of valuating them we propose to combine sustainability indicators and defensive expenditures for the implementation of public policies. This approach agrees with the environmental conservation paradigm implicit in sustainable development. It allows an estimation of the physical natural capital depreciation (PNCD), by using it to correct the gross domestic product (GDP) of the study area, and demonstrating the present non-sustainable characteristics of the current policies applied to the area.     

材料自然环境试验数据工程化应用方法探讨

目的研究探讨材料自然环境试验数据在装备设计选材和寿命预测方面的工程化应用方法。方法通过分析材料自然环境试验数据与装备实际使用状态的符合性原则,利用肖维奈准则和子样变异系数法对暴露于海南万宁的2A12铝合金抗拉强度试验数据进行处理。采用环境效应修正系数C-t曲线初步评价2A12铝合金在某型飞机上的工程应用情况及使用寿命。结果 2A12铝合金海洋大气环境下最终的使用年限为36年,满足在海洋大气环境服役使用要求,同时满足一般军用飞机最长30年日历寿命要求,可将2A12铝合金应用于机身、机翼上翼面、平尾、垂尾等机体主要部位。结论该方法初步实现了材料自然环境试验数据在某型飞机上的工程化应用。