锅炉烟尘测试有关问题探讨

锅炉烟尘测试方法中规定,在锅炉运行出力大于锅炉额定负荷７０％时的工况条件下,烟尘的测试结果才为有效。为此,应用有关数学公式进行计算,根据计算结果判断当时的锅炉运行工况是否符合测试要求,以避免无效监测。     

Resource utilization of typical biomass wastes as biochars in removing plasticizer diethyl phthalate from water: characterization and adsorption mechanisms

● Six largely produced agricultural biomass wastes were pyrolyzed into biochars. ● Feedstock type significantly determined physiochemical properties of biochars. ● The biochars showed powerful adsorption capabilities to Plasticizer DEP. ● Giant reed biochar with higher DEP adsorption was a prominent sorbent. Plastic pollution as a global environmental issue has become a research hotspot, among which the removal of inherent plasticizer (e.g., phthalic acid esters, PAEs) received increasing attention. However, the effects of biochars derived from different feedstocks on the adsorption of PAEs are poorly understood. Thus, the characteristics of biochars derived from six largely produced biomass wastes in China at 400 °C, as well as their performance in adsorption of diethyl phthalate (DEP), one of frequently detected PAEs in aqueous environment, were investigated. The results indicated that the variation in feedstock type showed significant changes in the properties (e.g., porosity, specific surface area, surface functional groups) of biochars, which affected DEP adsorption and desorption. Pseudo-second order and Freundlich models fitted the adsorption data well, and adsorption mechanisms mainly included hydrophobic effect, followed by micropore filling, hydrogen bonding, and π-π EDA interactions. Adsorption thermodynamics revealed that the adsorption was a spontaneous and exothermic the adsorption capacities of DEP on these biochars slightly decreased with the increasing pH but increased with the increasing ionic strength. Among these biochars, the giant reed biochar with relatively higher DEP adsorption and low desorption exhibited the great efficiency for DEP removal as an environment-friendly sorbent. These results highlighted the significant roles of micropore filling and hydrogen bond in determining adsorption capacity of designed biochars prepared from selecting suitable agricultural straws and wetland plant waste to typical plasticizer. The findings are useful for producing designed biochars from different biomass wastes for plasticizer pollution control.     

二级公路成为事故之路的症结

二级公路交通事故多发 ,其症结在于道路的规划、设计和管理工作中存在许多不完善并急需改进之处。例如交通参与人素质与道路不协调 ,道路交通安全设施不完善 ,道路规划、建设受到行政干预 ,公路平面交叉口不规范等。解决二级公路交通安全问题需要从规划、设计和管理等诸多方面入手。因此 ,笔者建议建立公路规划、设计安全审计和责任追究制度 ;在选用公路等级、设计速度和限制速度时 ,以公路功能定位 ;根据交通安全法律、法规规定及时完善交通安全设施 ;强化交叉路口规范化管理和支线限速设计 ;加强交通安全管理力度 ,增加科技管理投入 ;由政府牵头 ,依靠公路沿线乡镇、单位和学校 ,深入持久地进行交通安全宣传教育 ,提高公路沿线居民的交通安全意识。     

大检修开工后水冷器内漏呈现的问题

为确保水冷器的服役周期,针对大检修开工后水冷器内漏的问题,从设计寿命、使用检修以及定期检验等方面进行了讨论,在设计者根据工况特点合理确定水冷器设计寿命的基础上,使用单位和检验机构还应根据水冷器潜在失效模式有针对性地加强日常管理。建议水冷器的停工检修与定期检验应关注管束的使用寿命,以保证检修后水冷器能运行到下一检修周期。