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Formation of Soluble Complexes of Metals with Humic Acid and Its Environmental Significance
Authors:Ashok Kumar Pandey  Shri Dhar Pandey  Virendra Misra  P N Viswanathan
Institution:  a Ecotoxicology Section, Industrial Toxicology Research Centre, Lucknow, India
Abstract:In order to investigate the role of functional groups present in humic acid(s) (HA) during complex formation, water soluble complexes between HA isolated from soil and metals (Pb, Ca, As, Ni, Cr, Co, Cu, Cd, Fe, Mn, Mg and Zn) were prepared and subjected to infrared (IR) spectroscopy. the IR data revealed the involvement of the - OH group of humic acid in complex formation with all metals except copper and arsenic, whereas the - COOH group of HA was found to be the preferred site of binding for all the metals. the significance of findings in relation to detoxification of environmental pollutants is discussed in this paper.
Keywords:Complex formation  humic acid  infrared (IR) spectroscopy  bioavailability  detoxification
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