Persistence and Dissipation Kinetics of Spiromesifen in Chili and Cotton |
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Authors: | K K Sharma Cherukuri Sreenivasa Rao J K Dubey S K Patyal N S Parihar R S Battu Vandana Sharma Pratigya Gupta Anoop Kumar Kalpana Maisnam Jaya Balwinder Singh I D Sharma Amit Nath Tej Bahadur Gour |
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Institution: | (1) All India Network Project on Pesticide Residues, Division of Agricultural Chemicals, IARI, New Delhi, 110 012, India;(2) Department of Entomology, College of Agriculture, ANGRAU, Rajendranagar, Hyderabad, Andhra Pradesh, 500030, India;(3) Department of Entomology and Apiculture, Dr. Y. S. Parmar University of Horticulture and Forestry, Nauni, Himachal Pradesh, 173 230, India;(4) Department of Entomology, Rajasthan Agricultural University, Jaipur, Rajasthan, 302 018, India;(5) Department of Entomology, Punjab Agricultural University, Ludhiana, Punjab, 141 004, India |
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Abstract: | In a field study carried out at three different locations, the dissipation of spiromesifen on cotton and chili was studied
and its DT50, and DT99 were estimated at each location. Spiromesifen was sprayed on chili at 96 and 192 g a.i. ha−1 and cotton at 120 and 240 g a.i. ha−1. Samples of chili fruits were drawn at 0, 1, 3, 5, 7, 10, 15, 21, 30 days after treatment and that of cotton seed and lint
at first picking and harvest. Soil samples were drawn 30 days after treatment from 0 to 15 and 15 to 30 cm layer. Quantification
of residues was done on GC–MS in Selected Ion Monitoring (SIM) mode in mass range 271–274 m/z. The LOQ of this method was
found 0.033 μg g−1, LOD being 0.01 μg g−1. The DT50 of spiromesifen when applied at recommended doses in chili fruits was found to be 2.18–2.40 days. Ninety-nine percent degradation
was found to occur within 14.5–16.3 days after application. Residues of spiromesifen were not detected in cotton seed and
lint samples at the first picking. In soil, no residues of spiromesifen were detectable 15 days after treatment. |
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Keywords: | Spiromesifen Dissipation First order kinetics DT50 DT90 |
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