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以Cu-ZSM-5为催化剂乙烯选择性催化还原烟气脱硝的试验研究
引用本文:李云,胡将军,王磊,欧阳玲,陈熙,甘复兴.以Cu-ZSM-5为催化剂乙烯选择性催化还原烟气脱硝的试验研究[J].工业安全与环保,2009,35(8).
作者姓名:李云  胡将军  王磊  欧阳玲  陈熙  甘复兴
作者单位:1. 武汉大学资源与环境科学学院环境工程系,武汉,430079;武汉钢铁集团鄂城钢铁有限公司,湖北鄂州,436000
2. 武汉大学资源与环境科学学院环境工程系,武汉,430079
3. 武汉市环境卫生设计研究院,武汉,430070
摘    要:介绍了采用乙烯作为还原气体、Cu-ZSM-5为催化剂的烟气脱硝工艺流程.首先,研究了催化剂的制备方法,Na-ZSM-5分子筛作为催化剂载体,用浸渍法制成了不同负载量的Cu-ZSM-5分子筛催化剂.其次,研究了培烧条件对催化剂活性的影响,包括反应温度、气体流速以及反应气中O2的浓度等催化还原反应工艺参数.最后,研究了掺杂Ce4+离子对Cu-ZSM-5分子筛的活性影响.

关 键 词:乙烯  催化还原  烟气脱硝  催化剂

Experiment Study on the Selective Catalytic Reduction of NO_x with Ethylene and Catalyst Cu-ZSM-5
LI Yun,HU Jiang-jun,WANG Lei,OU Yang-ling,CHEN Xi,GAN Fu-xing.Experiment Study on the Selective Catalytic Reduction of NO_x with Ethylene and Catalyst Cu-ZSM-5[J].Industrial Safety and Dust Control,2009,35(8).
Authors:LI Yun  HU Jiang-jun  WANG Lei  OU Yang-ling  CHEN Xi  GAN Fu-xing
Institution:1.Department of Environmental Engineering;School of Resources and Environmental Science;Wuhan University Wuhan 430079
Abstract:This paper introduces the technology of flue gas denitrification by using ethylenee as reducer and Cu-ZSM-5 as catalyst.First it is studied the method to prepare the catalyst,in which Na-ZSM-5 is used as the catalyst carrier and Cu-ZSM-5 catalyst of different loading is prepared by macerate method and the effects of the fitting temperature on the catalytic activity are studied;then it is investigated the influencing factors in the reaction,such as the reaction temperature,gas flow rate and oxygen gas concen...
Keywords:ethylene deoxidize flue gas denitrification catalyst  
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