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Increased biodegradation of a low-density polyethylene (LDPE) matrix in starch-filled LDPE materials
Authors:Ann-Christine Albertsson  Camilla Barenstedt  Sigbritt Karlsson
Affiliation:(1) Department of Polymer Technology, The Royal Institute of Technology, S-100 44 Stockholm, Sweden
Abstract:Preheated14C-labeled LDPE-films with 15% corn starch and a proxidant formulation [masterbatch (MB)] incubated in aqueous solutions with fungi at ambient temperature are about three times more susceptible to biodegradation than the corresponding preheated pure LDPE as observed by liquid scintillation counting (LSC). The inbuilt induction time before autoxidation commences can be shortened by initial heating. Preheated LDPE-MB materials biodegrade about five times faster than nonheated ones. After 1 year of biodegradation of nonheated LDPE-MB, sporadic increases in the evolution of14CO2 have been noted, showing that the induction time may be running toward and end.
Keywords:Degradation  biodegradation  starch-filled  polyethylene  prooxidant  autoxidation
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