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海上含聚污水电化学处理装置的优化
引用本文:陈文娟,靖波,张健,孟凡雪.海上含聚污水电化学处理装置的优化[J].化工环保,2017,37(4):400-403.
作者姓名:陈文娟  靖波  张健  孟凡雪
作者单位:1. 海洋石油高效开发国家重点实验室,北京 100028;; 2. 中海油研究总院,北京 100028
基金项目:国家科技重大专项(2016ZX05025-003)
摘    要:为解决传统电化学方法在含聚污水处理时电极板消耗严重、絮渣量大的问题,通过改进电极板材料、组合数及结构等,研究适度降解-除油一体化电化学技术,在降低渣泥量的同时保证处理效果。实验结果表明:最佳电极板组合为"网状惰性金属复合物极板(阳)-网状铝极板(阴)-网状铝极板(阴)-网状惰性金属复合物极板(阳)";在电解电流为4.0 A、极板间距为8.0 cm、面体比(电极板面积与处理污水量的比值)为2/17 cm~2/mL、电解时间为30 min的最佳处理条件下,几乎无絮渣产出,含聚污水的浊度去除率为93.3%、聚合物降解率为92.0%、除油率为95.0%,展现了优良的处理效果。

关 键 词:海上油田  含聚污水  电化学处理  除油  电极板  
收稿时间:2016-11-11

Optimization of electrochemical treatment device for polymer-flooding produced wastewater in offshore oilfield
Chen Wenjuan,Jing Bo,Zhang Jian,Meng Fanxue.Optimization of electrochemical treatment device for polymer-flooding produced wastewater in offshore oilfield[J].Environmental Protection of Chemical Industry,2017,37(4):400-403.
Authors:Chen Wenjuan  Jing Bo  Zhang Jian  Meng Fanxue
Institution:1. State Key Laboratory of Offshore Oil Exploitation,Beijing 100028,China;2. CNOOC Research Institute,Beijing 100028,China
Abstract:Aiming at the serious loss of electrode plates and large amount of flocculated slug in traditional electrochemical treatment of polymer-flooding produced wastewater,the integrated electrochemical technology for oil degradation and removal was researched by optimizing material,amount and structure of electrode plate,in order to decrease the slug amount with good treatment effect. The experimental results showed that:The optimal combination of electrode plates was “mesh inert metal composite electrode (anode)-mesh aluminum plate (cathode)-mesh anode plate (cathode)-mesh inert metal composite electrode (anode)”;Under the optimum treatment conditions of electrolysis current 4.0 A,electrode spacing 8.0 cm,ratio of electrode plate area to wastewater volume 2/17 cm2/mL and electrolysis time 30 min,there was almost no flocculated slug produced,the removal rate of turbidity,oil and polymer of the wastewater were 93.3%,92.0%,95.0%,respectively,showing a good treatment effect of the technology.
Keywords:offshore oilfield  polymer-flooding produced wastewater  electrochemical treatment  oil removing  electrode plate  
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