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春季黄、渤海中异戊二烯的浓度空间分布与海-气通量
引用本文:吴英璀,李建龙,王健,张洪海,杨桂朋.春季黄、渤海中异戊二烯的浓度空间分布与海-气通量[J].中国环境科学,2018,38(3):893-899.
作者姓名:吴英璀  李建龙  王健  张洪海  杨桂朋
作者单位:1. 中国海洋大学化学化工学院, 山东 青岛 266100;2. 青岛海洋科学与技术国家实验室, 海洋生态与环境科学功能实验室, 山东 青岛 266071
基金项目:国家重点研发计划项目(2016YFA0601301);国家自然科学基金(41306069);中国科学院海洋研究所海洋生态与环境科学重点实验室开放基金(KLMEES201602);中央高校基本科研业务费项目(201513049)
摘    要:利用吹扫捕集-气质联用方法测定了2014年5月黄海、渤海所取海水样品中异戊二烯的含量,探讨了其分布特征、海-气通量及影响因素.研究结果表明:春季黄海、渤海海域表层海水中异戊二烯的浓度范围为6.02~32.91pmol/L,(平均值±标准偏差)为(15.39±4.98)pmol/L,在黄海中部海域出现浓度高值;表层海水中异戊二烯与叶绿素a(Chl-a)浓度有一定的正相关性(R2=0.2529,n=49,P < 0.001),说明浮游植物生物量在异戊二烯生产和分布中发挥重要作用;春季黄海、渤海异戊二烯海-气通量的变化范围为0.78~192.43nmol/(m2·d),(平均值±标准偏差)为(24.08±30.11)nmol/(m2·d),表明我国陆架海区是大气异戊二烯重要的源.

关 键 词:异戊二烯  分布特征  海-气通量  黄海  渤海  
收稿时间:2017-08-07

Spatial distribution and sea-to-air flux of isoprene concentration in the Yellow Sea and the Bohai Sea in spring
WU Ying-cui,LI Jian-long,WANG Jian,ZHANG Hong-hai,YANG Gui-peng.Spatial distribution and sea-to-air flux of isoprene concentration in the Yellow Sea and the Bohai Sea in spring[J].China Environmental Science,2018,38(3):893-899.
Authors:WU Ying-cui  LI Jian-long  WANG Jian  ZHANG Hong-hai  YANG Gui-peng
Institution:1. College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China;2. Laboratory for Marine Ecology and Chemistry and Environmental Science, Qingdao National Laboratory for Marine Science and Technology, Qingdao 266071, China
Abstract:Isoprene concentrations were determined by gas chromatography with mass spectrum detector (GC-MSD) coupled with purge-and-trap system to study the spatial distribution as well as sea-to-air flux and influencing factors.The results showed that the concentrations of isoprene ranged from 6.02 to 32.91pmol/L in the surface seawater of the Yellow Sea and the Bohai Sea in spring,with an average of (15.39±4.98) pmol/L.The highest concentration of isoprene was found in central Yellow Sea.A positive correlation was observed between isoprene and Chl-a concentrations (R2=0.2529,n=49,P <0.001),suggesting that phytoplankton play an important role in the production and distribution of isoprene.The sea-to-air flux ranged from 0.78 to 192.43nmol/(m2·d),with a mean value of (24.08±30.11) nmol/(m2·d).The study shows that the shelf seas of China might be an important source of isoprene.
Keywords:isoprene  distribution  sea-to-air flux  Yellow Sea  Bohai Sea  
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