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微波-Fenton氧化-PAFSi絮凝法处理含油废水
引用本文:施国飞,徐晓军,贾佳,郑鑫,管堂珍,陈晓鸿.微波-Fenton氧化-PAFSi絮凝法处理含油废水[J].环境污染治理技术与设备,2014(1):190-197.
作者姓名:施国飞  徐晓军  贾佳  郑鑫  管堂珍  陈晓鸿
作者单位:[1]昆明理工大学环境科学与工程学院,昆明650500 [2]浙江环科环境咨询有限公司,杭州310007
基金项目:青岛市新型环保技术重点实验室项目(02-2-kj-zhj-77)
摘    要:采用微波-Fenton氧化-PAFSi絮凝法处理含油废水,结果表明,200mL水样先经微波辐射6rnin,在pH=2,H2O2(30%)3.5g/L,Fe2+ 1.3g/L的条件下氧化4h后,采用聚硅酸铝铁(Al:Fe:Si=10:2:1)和聚丙烯酰胺在pH:8时进行絮凝实验,处理后废水浊度、SS、COD、含油量和色度分别降低了99.46%、96.66%、91.94%、97.97%和95.00%,且经处理后废水的BOD5/COD由原水的0.04提高到0.53。实验还分析了含油废水的降解机理。

关 键 词:含油废水  絮凝  Fenton氧化微波

Treatment of oily wastewater by microwave-Fenton oxidation-PAFSi flocculation
Shi Guofeix Xu XiaojunI Jia Jia,Zheng XinI Guan TangzhenI Chen Xiaohong.Treatment of oily wastewater by microwave-Fenton oxidation-PAFSi flocculation[J].Techniques and Equipment for Environmental Pollution Control,2014(1):190-197.
Authors:Shi Guofeix Xu XiaojunI Jia Jia  Zheng XinI Guan TangzhenI Chen Xiaohong
Institution:1. Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, 2. Zhejiang Environmental Sciences Limited Company of Environmental Consulting, Hangzhou 310007, China)
Abstract:The microwave-Fenton oxidation-flocculation method was investigated to treat the oily wastewater. In this study, 200 mL of wastewater was treated with microwave for 6 min, then oxidated 4 hours un- der the conditions of pH = 2, 3.5 g/L of H2 02 (30%) , 1.3 g/L of Fe2 +. Final poly aluminum silicate iron ( Fe :AI: Si = 10: 2:1 ) and polyacrylamide were used in the floeeulation experiment (pH =8). The results showed that the turbidity, SS, COD, oil content and chrominanee of effluent decreased by 99.46%, 96.66%, 91.94% , 97.97% and 95.00% ,respectively, the value of BODs/COD changed from 0.04 to 0.53 after treat- ment, which indicated that the water quality was improved greatly, and the treatment effect was remarkable. The degradation mechanisms of oily wastewater were also analyzed.
Keywords:wastewater containing oil  flocculation  Fenton oxidation  microwave
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