Observations of 2,4,6-trichlorophenol degradation by ozone

The aqueous reactivity of 2,4,6-trichlorophenol (TCP) with ozone has been studied at laboratory-scale using a simple gas bubble/liquid contacting system. Degradation rate constants were measured directly and found to be 7.6 and 77.2 M(-1)s(-1) at pH 2 and 7.5, respectively. At pH 7.5, 10 min of ozonation ( identical with 15 mM ozone consumption) achieved a 90% degradation of TCP, which corresponded to the release of approximately 2 mol Cl(-) per mol TCP. The presence of hydrogen peroxide in solution did not significantly increase the TCP degradation but increased the overall dechlorination to 2.7 mol Cl(-) per mol TCP. The presence of humic acid (HA) in solution was found to enhance the degradation rate of TCP at low relative HA concentrations (<0.6 g/g HA:TCP), but to reduce the rate at higher HA concentrations.