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部分水溶性偶氮染料的光催化降解研究
引用本文:孙平,陈景文.部分水溶性偶氮染料的光催化降解研究[J].环境化学,1999,18(3):254-257.
作者姓名:孙平  陈景文
作者单位:大连理工大学化工学院环境科学与工程系 大连.ll6012
基金项目:国家自然科学基金(No.29807001),辽宁省自然科学基金(No.962118)
摘    要:本研究以高压汞灯为光源,系统地研究了16种偶氮染料在水溶液中的TiO2光催化降解。结果表明,这些偶氮染料的光解为一级动力学反应,采用TiO2光催化降解方法处理所研究的偶氮染料是可行的,并初步探讨了染料的结构与光解反应表观速率常数之间的关系。

关 键 词:偶氮染料  光催化氧化  动力学  降解  废水处理

KINETICS OF PHOTOCATALYTIC OXIDATION OF SOME AZOIC DYES IN WATER SOLUTION
Sun Ping,Chen Jingwen,Quan Xie,Yang Fenglin Xue Darning,Zhao Yazhi,Chen Shuo.KINETICS OF PHOTOCATALYTIC OXIDATION OF SOME AZOIC DYES IN WATER SOLUTION[J].Environmental Chemistry,1999,18(3):254-257.
Authors:Sun Ping  Chen Jingwen  Quan Xie  Yang Fenglin Xue Darning  Zhao Yazhi  Chen Shuo
Abstract:Photocatalytic degradation of 16 azo-dyes in TiO2 suspension and irradiated by a high pressure mercury lamp has been studied. The results show that the use of photocatalytic reaction to treat wastewater containing azo-dyes is feasible, and the photocalytic reaction of each azo-dye follows pseudo-first-order kinetics. The initial qualitative relationships between molecular structure and the determined pseudo-first-order photocatalytic degradation rate constants for the azo-dyes under study are discussed.
Keywords:azo-dye  photocatalysis  kinetics  
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