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合成氨废水短程反硝化特性研究
引用本文:李妍,李泽兵,马家轩,王晓毅,赵白航,李军.合成氨废水短程反硝化特性研究[J].环境科学,2012,33(6):1902-1906.
作者姓名:李妍  李泽兵  马家轩  王晓毅  赵白航  李军
作者单位:1. 北京工业大学北京市水质科学与水环境恢复工程重点实验室,北京,100124
2. 河南省化工研究所有限责任公司,郑州,450052
基金项目:国家水体污染控制与治理科技重大专项(2009ZX07210-002); 北京市自然科学基金项目(8122005); 北京市教委重点项目(KZ201110005008)
摘    要:取自强化A/O工艺处理合成氨废水中试装置的活性污泥,在pH、碳源和温度均不为限制性因素条件下,短程反硝化和全程反硝化均为零级反应.结果表明,相对于全程反硝化,短程反硝化可以节约14.1%的碳源和55.7%的反硝化时间;初始NO2--N为36.82 mg.L-1时反硝化最快,比反硝化速率(以NO2--N/VSS计)为0.509 g.(g.d)-1;pH为7.5时反硝化速率最快,实际运行中应避免缺氧区pH〉9;选择性增殖的反硝化菌对甲醇和乙醇形成了良好的适应性,却对葡萄糖和乙酸等其它低分子易降解有机物产生了不适应性.

关 键 词:合成氨废水  短程反硝化  比反硝化速率  碳源
收稿时间:2011/8/24 0:00:00
修稿时间:2011/11/22 0:00:00

Characteristic Research of Shortcut Denitrification in Synthetic Ammonia Industrial Wastewater Treatment Process
LI Yan,LI Ze-bing,MA Jia-xuan,WANG Xiao-yi,ZHAO Bai-hang and LI Jun.Characteristic Research of Shortcut Denitrification in Synthetic Ammonia Industrial Wastewater Treatment Process[J].Chinese Journal of Environmental Science,2012,33(6):1902-1906.
Authors:LI Yan  LI Ze-bing  MA Jia-xuan  WANG Xiao-yi  ZHAO Bai-hang and LI Jun
Institution:Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery Engineering, Beijing University of Technology, Beijing 100124,China;Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery Engineering, Beijing University of Technology, Beijing 100124,China;Henan Chemical Industry Research Institute Co. Ltd., Zhengzhou 450052, China;Henan Chemical Industry Research Institute Co. Ltd., Zhengzhou 450052, China;Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery Engineering, Beijing University of Technology, Beijing 100124,China;Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery Engineering, Beijing University of Technology, Beijing 100124,China
Abstract:Active sludge was from a pilot-scale synthetic ammonia industrial wastewater treatment plant with a strengthen anoxic-oxic (A/O) technology. The zero order kinetic model was suit for describing shortcut and complete denitrification process.Experimental results showed that shortcut denitrification could reduce 14.1% carbon source consumption and 55.7% denitrification time, respectively, comparing with complete denitrification. The maximum specific denitrification rate was 0.509 g·(g·d)-1 with an initial NO2--N concentration of 36.82 mg·L-1 and pH 7.5. In the industrial practice, it must be avoided pH higher than 9.0 in anoxic zone for industrial treatment. Replication-selective denitrifying bacteria showed a strong adaptability to methanol and ethanol, but showed maladaptation to other small molecular and easily biodegradable organics, such as glucose and acetic acid.
Keywords:synthetic ammonia wastewater  shortcut denitrification  specific denitrification rates  carbon source
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