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初始pH值和物料配比对高温混料厌氧发酵进程的影响
引用本文:张彤,翟宁宁,王晓娇,秦新苗,杨改河. 初始pH值和物料配比对高温混料厌氧发酵进程的影响[J]. 环境科学学报, 2016, 36(7): 2571-2579
作者姓名:张彤  翟宁宁  王晓娇  秦新苗  杨改河
作者单位:1. 西北农林科技大学农学院, 杨凌 712100;2. 陕西省循环农业工程技术研究中心, 杨凌 712100,1. 西北农林科技大学农学院, 杨凌 712100;2. 陕西省循环农业工程技术研究中心, 杨凌 712100,1. 西北农林科技大学农学院, 杨凌 712100;2. 陕西省循环农业工程技术研究中心, 杨凌 712100,西北农林科技大学农学院, 杨凌 712100,1. 西北农林科技大学农学院, 杨凌 712100;2. 陕西省循环农业工程技术研究中心, 杨凌 712100
基金项目:西北农林科技大学博士科研启动基金(No.Z109021403);中央高校基本科研业务费(No.Z109021511)
摘    要:
为了研究高温条件下初始p H对厌氧发酵进程的影响,以猪粪、玉米秸秆为发酵原料,设置3种比例(干物质质量比30∶70、50∶50、70∶30)下6个水平(6.0、6.5、7.0、7.5、8.0的初始p H值以及一个不调控初始p H的处理作为对照)进行批次发酵试验.结果表明,初始p H值和物料配比都会显著影响厌氧发酵过程的启动时间和甲烷产量.当初始p H值为7.0时,VS降解率趋于稳定.COD去除率随着粪便含量的增加而逐渐降低.高温猪粪玉米秸秆混合发酵最佳挥发性脂肪酸(VFA)/碱度比值范围为0.05~0.3;猪粪可以作为一种缓冲材料,适量添加可增大消化系统的缓冲能力.通过建模优化,预测出当初始p H值为6.95、猪粪/玉米秆为70∶30时,可得到每克挥发性固体最大理论单位甲烷产量169.22 m L·g-1.

关 键 词:高温厌氧发酵  初始pH值  粪秆比例  最适条件
收稿时间:2015-08-09
修稿时间:2015-09-11

Effect of initial pH and mixture ratio on thermophilic anaerobic co-digestion of swine manure and maize stalk
ZHANG Tong,ZHAI Ningning,WANG Xiaojiao,QIN Xinmiao and YANG Gaihe. Effect of initial pH and mixture ratio on thermophilic anaerobic co-digestion of swine manure and maize stalk[J]. Acta Scientiae Circumstantiae, 2016, 36(7): 2571-2579
Authors:ZHANG Tong  ZHAI Ningning  WANG Xiaojiao  QIN Xinmiao  YANG Gaihe
Affiliation:1. College of Agronomy, Northwest A&F University, Yangling 712100;2. The Research Center of Recycle Agricultural Engineering and Technology of Shaanxi Province, Yangling 712100,1. College of Agronomy, Northwest A&F University, Yangling 712100;2. The Research Center of Recycle Agricultural Engineering and Technology of Shaanxi Province, Yangling 712100,1. College of Agronomy, Northwest A&F University, Yangling 712100;2. The Research Center of Recycle Agricultural Engineering and Technology of Shaanxi Province, Yangling 712100,College of Agronomy, Northwest A&F University, Yangling 712100 and 1. College of Agronomy, Northwest A&F University, Yangling 712100;2. The Research Center of Recycle Agricultural Engineering and Technology of Shaanxi Province, Yangling 712100
Abstract:
The thermophilic anaerobic digestion of swine manure and maize stalk as main substrates were conducted in batch and the effect of initial pH was investigated. Five different initial pH levels (6.0, 6.5, 7.0, 7.5 and 8.0) and one uncontrolled level were tested with three manure/stalk ratios (30:70, 50:50, and 70:30). Both initial pH and mixture ratio significantly affected the lag phase and methane yield from anaerobic digestion. Results showed that (COD) removal rate decreased with the increase of manure content. When the initial pH was 7.0, the degradation rate of volatile solid (VS) was stable. The optimum ratio of volatile fatty acids (VFA) to alkalinity for thermophilic digestion of swine manure and maize stalk was 0.05~0.3. Adding manure increased the buffering capacity of fermentation system. The theoretical maximum methane yield was 169.22 mL·g-1, when the initial pH was 6.95 and the manure/stalk ratio was 70:30.
Keywords:thermophilic anaerobic digestion  initial pH  manure/stalk ratio  optimum condition
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