Urban energy mining from sewage sludge

This work showed that sewage sludge could be a strong candidate for biodiesel production. High lipid content (18–20%) with C_16?18-carbon range was experimentally identified and measured. These lipids from sewage sludge were converted into biodiesel via the transesterification reaction with MgO–CaO/Al₂O₃ derived from magnesium slag, and biodiesel conversion was ～98%. The experimental work enabled explaining that temperature is the main driving force for the transesterification reaction, which can be enhanced in the presence of CO₂. This also enables combination of esterification of free fatty acids and transesterification of triglycerides into a single process within 1 min in the temperature range of 350–500 °C. Sewage sludge residue after extracting lipids was also a good feedstock for recovering energy via thermo-chemical processes. The impact of CO₂ co-feed on the pyrolysis/gasification process of SS residue was also investigated in this work. The CO₂ injected into the thermo-chemical process remarkably increased the generation of CO by a factor of 2. Moreover, the introduction of CO₂ into the pyrolysis/gasification process enabled reducing condensable hydrocarbons (tar) by expediting cracking; thus, utilizing CO₂ as chemical feedstock for the gasification process not only leads to higher thermal efficiency but also has environmental benefits.