| ECD氧气诱导法分析大气中痕量HCFC-22 |
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| 引用本文： | 孙皓林,陈立民,乐致威,孙国忠,马蔚纯.ECD氧气诱导法分析大气中痕量HCFC-22[J].环境科学,2001,22(4):21-24. |
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| 作者姓名： | 孙皓林 陈立民 乐致威 孙国忠 马蔚纯 |
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| 作者单位： | 复旦大学环境科学与工程系,上海,200433 Email:haolins@hotmail.com |
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| 基金项目： | 国家自然科学基金资助项目(29677002);高等学校骨干教师资助计划项目. |
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| 摘 要： | HCFC-22(CHClF2)是CFC-12的主要替代物,它在大气中的体积分数仅为10-12级.而且对ECD检测器响应灵敏度很低.本文经过低温浓缩进样后采用氧气诱导法来增强ECD对它的分析灵敏度,载气中氧气的体积分数为0.54%时,信噪比最大,此时ECD灵敏度增强约500倍.结合该条件下ECD温度选择、程序升温和载气流量的研究,建立了高灵敏度ECD气相色谱测定大气中HCFC-22浓度的实用分析方法.
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| 关 键 词： | HCFC22 GCECD 氧气诱导法 |
| 文章编号： | 0250-3301(2001)04-04-0021 |
| 收稿时间： | 2000/9/21 0:00:00 |
| 修稿时间： | 2000年9月21日 |
Measurement of Chlorodifluoromethane(HCFC-22)in the Atmosphere by Using an O2-Induced Electron Capture Detector (ECD) |
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| Sun Haolin,Chen Limin,Yue Zhiwei,Sun Guozhong and Ma Weichun.Measurement of Chlorodifluoromethane(HCFC-22)in the Atmosphere by Using an O2-Induced Electron Capture Detector (ECD)[J].Chinese Journal of Environmental Science,2001,22(4):21-24. |
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| Authors: | Sun Haolin Chen Limin Yue Zhiwei Sun Guozhong and Ma Weichun |
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| Institution: | Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China. haolins@hotmail.com |
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| Abstract: | Chlorodifluoromethane ( CHClF2, HCFC-22),a typical substitute of dichlorodifluoromethane(CF2Cl2,CFC-12),which atmospheric concentration was only at 10-12V/V level.After preconcentrated air sample,O2-Induced method was used to enhance sensitivity of ECD response to HCFC-22.When O2 concentration in carrier gas was 0.54%,there was the greatest value of S/N(signal to noise) and ECD response increased by about 500 times.With the study of other conditions, such as selection of the ECD temperature, programing of the column oven temperature and carrier gas flow,a practicable analysis method with high sensitivity of ECD was established. |
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| Keywords: | HCFC 22 GC ECD O 2 induced |
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