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无机阴离子对电化学氧化降解水体中4-CP的影响
引用本文:竺浩炜,汤金如,徐志荣.无机阴离子对电化学氧化降解水体中4-CP的影响[J].环境科学与管理,2010,35(10):83-86.
作者姓名:竺浩炜  汤金如  徐志荣
作者单位:[1]浙能乐清发电有限责任公司,浙江乐清325609 [2]安阳市市政设计研究院有限责任公司,河南安阳455000 [3]河海大学环境学院,江苏南京210098
摘    要:为了探讨废水中无机阴离子对电化学氧化降解对氯苯酚(4-CP)产生的影响。文章采用了自制圆形电化学反应器,通过改变模拟废水中电解质及其浓度来分析无机阴离子对4-CP去除率及矿化率的影响。试验研究表明,当废水中以OH-为主且浓度约为0.01 mol/L时,4-CP去除率可达81.99%,矿化率最高可达38.09%,而电化学能耗最低仅为35.57 kWh。

关 键 词:无机阴离子  电化学氧化  对氯苯酚  电化学能耗  废水处理

Influences of Inorganic Anions on Degradation of p-Chlorphenol in the Water by Electrochemical Oxidation
Zhu Haowei,Tang Jinru,Xu Zhirong.Influences of Inorganic Anions on Degradation of p-Chlorphenol in the Water by Electrochemical Oxidation[J].Environmental Science and Management,2010,35(10):83-86.
Authors:Zhu Haowei  Tang Jinru  Xu Zhirong
Institution:1.Zhejiang Energy Yueqing Power Generation Co.Ltd,Yueqing 325609,China;2.Anyang.Municipal Engineering Design Instituted Co.Ltd,Anyang 455000,China;3.College of Environment,Hehai University,Nanjing 210098,China)
Abstract:P-Chlorphenol was selected as a model pollution substrate.The influences of inorganic anions on its degradation were investigated in the wastewater by changed the supporting electrolyses and its concentration at ambient temperature and pressure.Results showed that 4-CP could be removed efficiently by electrical chemistry oxidation with 81.99% removal rate when the concentration of OH-was about 0.01 mol/L in 2.5hours,the mineralization rate of 4-CP was up to 38.90%,and the electrochemical energy consumption was the lowest that was just only 35.57 kWh/(kg4-CP).
Keywords:inorganic anions  electrical chemistry oxidation  p-Chlorphenol  electrochemical energy consumption  wastewater treatment
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