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类Fenton氧化—好氧移动床生物膜法处理抗生素发酵废水
引用本文:邢子鹏,商佳吉,孙德智.类Fenton氧化—好氧移动床生物膜法处理抗生素发酵废水[J].环境污染与防治,2009,31(1).
作者姓名:邢子鹏  商佳吉  孙德智
作者单位:哈尔滨工业大学市政环境工程学院,黑龙江,哈尔滨,150090
基金项目:国家重点基础研究发展规划(973计划) 
摘    要:采用类Fenton氧化-好氧移动床生物膜(MBBR)法处理难降解抗生素发酵废水,探讨了H2O2和草酸投加量对类Fenton氧化工艺以及HRT和曝气量对好氧MBBR反应器的影响.实验结果表明,当类Fenton氧化工艺的最佳操作参数为反应溶液H2O2和草酸初始质量浓度分别为150、45 mg/L、30 W/154 nm紫外灯照射1 h、pH为3.0,在曝气搅拌条件下,COD平均去除率为80.9%.当类Fenton氧化工艺出水pH在7.0时,废水中的污染物还可以进一步被混凝去除.好氧MBBR反应器的最佳工艺参数为HRT 12 h、曝气量0.10 m3/h以及填料填充比(体积比)30%,最终废水COD平均去除率为99.1%,达到<污水综合排放标准>(GB 8978-1996)三级标准要求.

关 键 词:抗生素发酵废水  类Fenton氧化  好氧移动床生物膜

Enhanced Fenton oxidation and biodegradation in aerobic moving bed biofilm reactor for treatment of antibiotic fermentation wastewater
Xing Zipeng,Shang Jiaji,Sun Dezhi.Enhanced Fenton oxidation and biodegradation in aerobic moving bed biofilm reactor for treatment of antibiotic fermentation wastewater[J].Environmental Pollution & Control,2009,31(1).
Authors:Xing Zipeng  Shang Jiaji  Sun Dezhi
Institution:School of Municipal & Environmental Engineering;Harbin Institute of Technology;Harbin Heilongjiang 150090
Abstract:The enhanced Fenton oxidation and biodegradation in an aerobic moving bed biofilm reactor (MBBR) was employed for the treatment of a high concentration refractory antibiotic fermentation wastewater. The raw wastewater was pretreated by coagulation and sedimentation using polymeric iron sulfate (PFS) as the coagulant to remove about 50% of organic loading and to provide the essential Fe2+ for the subsequent Fenton oxidation,which was enhanced by UV irradiation and the addition of oxalic acid to achieve furth...
Keywords:COD
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