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非常规天然气采出水处理现状及建议
引用本文:高明龙,贾媛,夏立全,马栋.非常规天然气采出水处理现状及建议[J].能源环境保护,2020,34(2):8-13.
作者姓名:高明龙  贾媛  夏立全  马栋
作者单位:煤炭科学技术研究院有限公司,北京100013;煤炭资源高效开采与洁净利用国家重点实验室,北京100013;国家能源煤炭高效利用与节能减排技术装备重点实验室,北京100013
基金项目:天地科技股份有限公司科技创新创业资金专项项目:非常规天然气采出水高级氧化COD脱除技术研究(2018-TD-MS008)。
摘    要:介绍了非常规天然气采出水水质特点与回用要求,分析了预处理、二级处理、脱盐处理等单元的技术研究进展与潜在问题。分析认为:非常规天然气采出水水质复杂,呈现高COD、高TDS、高硬度、高氯化物等水质特征;针对有机物脱除难题,需进一步开发耐盐催化氧化技术、耐盐生化技术和高效抗污染膜浓缩新工艺;脱盐处理等单元应通过高级氧化工艺进一步降低有机物含量,促进浓缩结晶系统的稳定运行和结晶盐的资源化。

关 键 词:非常规天然气  采出水  处理技术  废水脱有机物  废水脱盐

Current situation of treatment of unconventional natural gas produced water
GAO Minglong,JIA Yuan,XIA Liquan,MA Dong.Current situation of treatment of unconventional natural gas produced water[J].Energy Environmental Protection,2020,34(2):8-13.
Authors:GAO Minglong  JIA Yuan  XIA Liquan  MA Dong
Institution:(China Coal Research Institute,Beijing 100013,China;State Key Lab of High Efficient Mining and Clean Utilization of Coal Resources,Beijing 100013,China;National Energy Technology&Equipment Laboratory of Coal Utilization and Emission Control,Beijing 100013,China)
Abstract:The water quality and reuse requirements of wastewater produced during unconventional natural gas extraction were introduced.The research process and potential problems of pretreatment,enhanced treatment and desalination treatment technologies were analyzed.The results show that unconventional natural gas produced water has high concentrations of COD,TDS,chloride and high hardness,thus its water quality is complex.In order to remove organic effectively,it is necessary to develop new technologies such as salt-tolerant catalytic oxidation technology,salt-tolerant biochemical technology and anti-pollution membrane concentrate technology.It is suggested to further reduce organic content by applying advanced oxidation processes in desalination units for the stable operation of concentration and crystallization system and utilization of salt.
Keywords:Unconventional gas  Produced water  Processing technology  Removal of organics from wastewater  Wastewater desalination
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