| Sensitized effect of β-cyclodextrin on the fluorescence in the determination of carbaryl |
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| 作者姓名： | LIU Wen-li TANG Bo |
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| 作者单位： | [1]CollegeofLifeSciencesandMedicineChemicalEngineering,TaizhouUniversity,Taizhou317000,China [2]CollegeofChemistry,ChemicalEngineeringandMaterialsScience,ShandongNormalUniversity,Jinan250014,China |
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| 基金项目： | TheNationalNaturalScienceFoundationofChina(No.2 99750 1 6)andtheImportantNaturalScienceFoundationofShandongProvince(No .Z2 0 0 0B0 3) |
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| 摘 要： | Based on the significant enhancement of fluorescence intensity of carbaryl in inclusion complex, a spetrofluorimetdc method with high sensitivity was developed for the determination of carbaryl in aqueous solution. Under the optimum conditions, the complex had excitation and emission maxima at 278 nm and 332 nm, respectively. The linear range of the method was 7.0 ng/ml-1500 ng/ml with a detection limit of 1.2 ng/ml. The proposed method was successfully used to determine quantitativelv of carbarvl in cottonseeds.
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| 关 键 词： | β-环式糊精 荧光性 胺甲萘 杀毒剂 农药 环境保护 |
| 收稿时间： | 2003/10/30 0:00:00 |
| 修稿时间： | 1/4/2004 12:00:00 AM |
Sensitized effect of beta-cyclodextrin on the fluorescence in the determination of carbaryl |
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| LIU Wen-li,TANG Bo.Sensitized effect of beta-cyclodextrin on the fluorescence in the determination of carbaryl[J].Journal of Environmental Sciences,2004,16(5):829-831. |
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| Authors: | Liu Wen-Li Tang Bo |
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| Institution: | College of Life Sciences and Medicine Chemical Engineering, Taizhou University, Taizhou 317000, China. liuwenlidy@yahoo.com.cn |
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| Abstract: | Based on the significant enhancement of fluorescence intensity of carbaryl in inclusion complex, a spetrofluorimetric method with high sensitivity was developed for the determination of carbaryl in aqueous solution. Under the optimum conditions, the complex had excitation and emission maxima at 278 nm and 332 nm, respectively. The linear range of the method was 7.0 ng/ml-1500 ng/ml with a detection limit of 1.2 ng/ml. The proposed method was successfully used to determine quantitatively of carbaryl in cottonseeds. |
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