利用养殖场废水厌氧发酵生物制氢技术研究

在批式厌氧反应器中,以厌氧消化污泥作为天然产氢菌源,通过养殖场废水的厌氧发酵生产氢气,考察了厌氧污泥和碳氮营养物质对养殖场废水产氢的影响,并对液相产物的分布、产氢动力学进行了分析.试验分为4个处理.结果表明,加入营养物质接种污泥的养殖场废水氢气含量、累积产氢量和单位COD氢气产量最高可达到50.65%、334.80mL和287.10mL/g.而未接种污泥的原始养殖场废水累积产氢量和单位COD氢气产量仅为59.24mL和67.05mL/g.污泥和碳氮营养物质对产氢能力均有显著地促进作用,加入碳氮源后微生物群促进了原养殖废水有机物的氢的形成.液相末端产物中,乙酸、丁酸占总挥发酸的61%～86%,产氢过程属于典型的乙酸-丁酸型发酵.总挥发性酸含量的提高,其产氢能力也增大. Gompertz模型能够很好地拟合其产氢过程.

Biohydrogen Production by Anaerobic Fermentation from Manure Wastewater

Biohydrogen production by anaerobic sludge was studied by using manure wastewater as substrate, in batch process. The influences of sludge and carbon nitrogen nutrition on hydrogen production, the liquid fermentative products and hydrogen dynamics were investigated. The results indicate both sludge and nutrition were able to enhance the hydrogen production. It can be obtained maximum hydrogen content 50.65%, cumulative hydrogen production 334.80mL and hydrogen yield per COD 287.10 mL/g from manure wastewater with carbon nitrogen nutrition and sewage sludge. However, the cumulative hydrogen production and the hydrogen yield per COD were only 59.24 mL and 67.05 mL/g from raw wastewater. Acetic acid and butyric acid in the effluent of fermentation occupied 61%-86%. It might be acetic-butyric acid type fermentation in the batch reactor. The more the VFA content, the higher the hydrogen yield. A modified Gompertz model can adequately describe the H₂ production.