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Destruction of Chlorofluorocarbons in a Cement Kiln
Authors:Hiroyuki Ueno  Yoshiharu Iwasaki  Sukehisa Tatsuichi  Masataka Soufuku
Institution:The Tokyo Metropolitan Research Institute for Environmental Protection , Tokyo , Japan
Abstract:Abstract

One of the thermal oxidation technologies recommended by the United Nations Environment Programme (UNEP) is destruction of chlorofluorocarbons (CFCs) in a cement kiln. The destruction of CFC12, CFC11 and CFC113 was studied in a cement kiln plant in actual commercial operation. CFCs were completely destroyed in the kiln under normal operating conditions. Hydrogen fluoride and hydrogen chloride generated by CFC decomposition were absorbed by cement materials. No formation of toxic ha-logenated organic compounds, such as polychlorinated dibenzo-p-dioxins or dibenzofurans (PCDDs/PCDFs), was observed in the CFC incineration.
Keywords:
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