Leaching characteristics of bisphenol A from epoxy-resin pavement materials |
| |
Authors: | Hiromi Sakamoto Shigenori Shoji Hidehiro Kaneko |
| |
Affiliation: | 1. Kanagawa Environmental Research Center , 1-3-39 Shinomiya, Hiratsuka, Kanagawa, 254-0014, Japan sakamoto@k-erc.pref.kanagawa.jp;3. Kanagawa Environmental Research Center , 1-3-39 Shinomiya, Hiratsuka, Kanagawa, 254-0014, Japan;4. Interdisciplinary Graduate School of Medicine and Engineering, University of Yamanashi , 4-3-11 Takeda, Kofu, Yamanashi, 400-8511, Japan |
| |
Abstract: | We investigated the leaching characteristics of bisphenol A (BPA) from two kinds of epoxy-resin pavement materials, one containing epoxy resins (EPs) and the other containing epoxy-acrylate resins (EPAs). Both samples contained residual BPA monomer, at levels of 9.0?µg?g?1 for the EP resin sample and 4.4?µg?g?1 for the EPA resin sample. These amounts were larger than amounts previously measured for polycarbonate samples. The amount of BPA leached from the samples increased with temperature. The leaching of BPA from EP was more strongly affected by temperature than the leaching from EPA. The pH also affected the amount of leached BPA. The maximum leached amount was observed under alkaline conditions (pH 10.8) for both sample types. The amounts of BPA that might leach from pavement materials during 1?h of heavy rain were estimated to be 0.9?µg?m?2 for EP and 3.5?µg?m?2 for EPA. Our results indicate that EPs disposed of in waste landfills without any treatment may be a source of BPA in leachate at landfill sites. |
| |
Keywords: | Epoxy acrylate serial batch leaching test pH buffer solution ionic strength |
|
|