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CNTs/TiO2/CS光降解苯的动力学
引用本文:曾丽萍,张泉,张国强.CNTs/TiO2/CS光降解苯的动力学[J].环境工程学报,2013,7(9):3517-3524.
作者姓名:曾丽萍  张泉  张国强
作者单位:湖南大学土木工程学院;湖南工程学院建筑工程学院
基金项目:广东省产学研项目(2008B090500232);教育部重点项目(2009-41);教育部博士点基金项目(20090161110016);湖南省杰青项目(11JJ1009);湖南省环保厅项目(湘财建指[2010]175)
摘    要:综合光催化氧化苯的动力学过程、光辐射场模型和质量守恒定律,采用平板型反应器建立了碳纳米管/二氧化钛/壳聚糖(CNTs/TiO2/CS)催化薄膜光催化氧化气相苯的数学模型;该模型考虑了光强、相对湿度、初始浓度与气体流速对气相苯光降解的影响。结果表明,建立的数学模型与实验结果吻合较好。

关 键 词:光催化    动力学模型

Kinetics of photocatalytic degradation benzene by CNTs/TiO2/CS film
Zeng Liping,Zhang Quan and Zhang Guoqiang.Kinetics of photocatalytic degradation benzene by CNTs/TiO2/CS film[J].Techniques and Equipment for Environmental Pollution Control,2013,7(9):3517-3524.
Authors:Zeng Liping  Zhang Quan and Zhang Guoqiang
Institution:Zeng Liping;Zhang Quan;Zhang Guoqiang;College of Civil Engineering,Hunan University;Department of Building Engineering,Hunan Institute of Engineering;
Abstract:We combined kinetic process of photocatalytic oxidation of benzene, radiation field model and the conservation of mass. The kinetic reaction rate model was suggested to describe the photocatalytic degradation of gaseous benzene about carbon nano tubes/TiO2/chitosan (CNTs/TiO2/CS) thin films by using plat-plate reactor. The influence of the indoor conditions such as light intensities, relativity humidities, flow rates and initial concentrations was analyzed in this model. Based on the results of calculation and experiments, a good agreement exists between the predictions from the model and the experimental results, which indicates the validity of the proposed kinetic model.
Keywords:photocatalytic  benzene  kinetics model
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