Nitrous oxide dynamics in a braided river system, New Zealand

Recently the Intergovernmental Panel on Climate Change (IPCC) emission factor EF5-r was revised downward to a value of 0.0025 kg N?O-N per kg NO?-N leached. It was not reduced further due to the continued uncertainty surrounding the dynamics of N?O in river systems. There have been few studies where river system N?O yields and fluxes have been measured. In this study, we examined the relationship between NO?-N and N?O-N fluxes at 10 sites along a braided river system (84 km) over a 397-d period. Isotopic analysis of NO?-N river water samples and the potential agricultural nitrogen (N) sources demonstrated that the NO?-N came from agricultural or sewage sources. Percent saturation of N?O varied with site and date (average, 114%) and correlated with river N?O-N concentrations. Modeled N?O fluxes (16-30 μg m(-2) h(-1)) from five sites were strongly related to river NO?-N concentrations ( r2 = 0.86). The modeled N?O-N fluxes ranged from 39 to 81% of the IPCC-derived emissions based on the NO?-N load in the river over 397 d and do not support further lowering of the EF5-r. Further in situ river studies are required to verify the N?O-N fluxes and the calculated gas transfer velocity values for these braided river systems.