敌敌畏的臭氧氧化处理

在12 L的反应器中,观察了臭氧浓度分别为4.9、6.7和7.6 mg/L,溶液温度10.50℃,pH值为3.1、5.3、7.2、9.4和11.2条件下,臭氧氧化浓度为30 mg/L的有机磷杀虫剂敌敌畏的处理效果,并计算了臭氧氧化敌敌畏的反应动力学.结果表明,臭氧氧化法是处理敌敌畏的高效方法.不同浓度臭氧处理5 min时敌敌畏的去除率均在96%以上,6.7 mg/L的臭氧氧化处理敌敌畏4 min时矿化度(以TOC 计)可达34.8%.臭氧浓度越高,敌敌畏的降解速率越快.随着敌敌畏初始浓度的升高,敌敌畏的氧化去除率下降,但绝对去除量升高.试验范围内的pH值和温度对敌敌畏的臭氧氧化去除效果影响不大.在臭氧浓度6.7 mg/L,pH 7.2和室温20℃的条件下,臭氧氧化敌敌畏的反应级数为0.11,反应速率常数k为7.72 mg·(L·min)-1.

Treatment of Dichlorvos by Ozone Oxidation

The dichlorvos of organophosphates was oxidized by ozone in a reactor of 12 L, when its initial concentrations was 30 mg/L, ozone concentrations was 4.9, 6.7 and 7.6 mg/L, pH was 3.1, 5.3, 7.2, 9.4, 11.2 and temperature was 10-50 degrees C, and the reaction kinetics of the treatment of dichlorvos by ozone were discussed. The results show that ozonation is an efficient way for treating dichlorvos. The removals of dichlorvos are all over 96% in 5 min ozonation. When ozone concentration is 6.7 mg/L, mineralization rate in TOC reaches 34.8% in 4 min. The degradation rate of dichlorvos increases as the ozone concentration increases but descends as its initial concentration increases. The removal effect of dichlorvos is roughly independent of pH value and temperature. When ozone concentration is 6.7 mg/L at pH 7.2 in room temperature, the ozonation reaction order of dichlorvos is about 0.11 and the reaction rate constant is 7.72 mg x (L x min)(-1).