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Integration studies on a two-stage fermentation process for the production of biohydrogen
Authors:Domenico Foglia  Mattias Ljunggren  Walter Wukovits  Anton Friedl  Guido Zacchi  Krzysztof Urbaniec  Mariusz Markowski
Institution:1. Vienna University of Technology, Getreidemarkt 9/166-2, 1060 Vienna, Austria;2. Lund University, P.O. Box 124, 221 00 Lund, Sweden;3. Warsaw University of Technology, Plock Campus, Jachowicza 2/4, 09-402 Plock, Poland;1. Department of Civil and Mechanical Engineering, University of Cassino and Southern Lazio, via Di Biasio 43, 03043 Cassino, FR, Italy;2. Department of Civil, Architectural and Environmental Engineering, University of Naples Federico II, via Claudio 21, 80125 Naples, Italy;3. Department of Mathematics and Applications Renato Caccioppoli, University of Naples Federico II, via Cintia, Monte S. Angelo, I-80126 Naples, Italy;4. UNESCO-IHE Institute for Water Education, Westvest 7, 2611 AX Delft, The Netherlands;1. Department of Civil and Environmental Engineering, Center for Engineering Innovation, University of Windsor, 401 Sunset Ave., Windsor, ON, Canada N9B 3P4;2. Great Lakes Institute for Environmental Research, University of Windsor, 401 Sunset Ave., Windsor, ON, Canada N9B 3P4;3. The Department of Biological Sciences, University of Windsor, 401 Sunset Ave., Windsor, ON, Canada N9B 3P4;1. Department of Applied Biotechnology and Food Science, Faculty of Chemical Technology and Biotechnology, Budapest University of Technology and Economics, H-1111 Budapest, Muegyetem rkp. 3, Hungary;2. Stan Mayfield Biorefinery, University of Florida, Perry, FL 32348, United States;3. Microbiology & Cell Science, University of Florida, Gainesville, FL 32611-0700, United States;1. Plock Branch of Warsaw University of Technology, Plock, Poland;2. Food Based Research, Wageningen, The Netherlands
Abstract:Fermentation of biomass residues and second generation biomasses is potentially a way to enable a sustainable production of hydrogen. Simulation models which calculate mass and energy balances, developed with Aspen Plus®, are used to integrate the process steps necessary to produce pure hydrogen from biomass in a 2-stage fermentation process. Process and heat integration are introduced to reduce the high water and heat demand of the process, connected to the low substrate concentrations in the involved process streams. The results show that the recirculation of process effluents, together with the use of properly designed heat exchangers, can reduce the water and heat demand up to 90% from a non-integrated process, but is also subject to restrictions due to an increase in osmolality in the system.
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