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Biocrude oils from the fast pyrolysis of poultry litter and hardwood
Authors:FA Agblevor  S Beis  SS Kim  R Tarrant  NO Mante
Institution:1. Carbolea Research Group, Department of Chemical and Environmental Science, University of Limerick, Ireland;2. Materials and Surface Science Institute, University of Limerick, Ireland;1. Thermochemical Processes Group (GPT), Aragón Institute for Engineering Research (I3A), Universidad de Zaragoza, Edificio I+D, C/ Mariano Esquillor s/n, 50018 Zaragoza, Spain;2. Laboratoire de Thermique Energétique et Procédés, Université de Pau et des Pays de l’Adour, 64000, Pau, France;1. Chemical and Environmental Science Department, University of Limerick, Ireland;2. University College Dublin, Dublin, Ireland;1. Environmental Engineering Department, Middle East Technical University, Ankara, Turkey;2. Environmental Engineering Department, Suleyman Demirel University, Isparta, Turkey;1. Department of Chemical and Biological Engineering, University of Saskatchewan, Saskatoon, SK, Canada S79 5C5;2. Saskatchewan Research Council, Saskatoon, SK, Canada S7N 2X8;1. University of Leuven, Department of Chemical Engineering, Process Engineering for Sustainable Systems, W. De Croylaan 46, B-3001 Leuven, Belgium;2. BMC Moerdijk, Middenweg 36a, 4782 PM Moerdijk, The Netherlands
Abstract:The safe and economical disposal of poultry litter is becoming a major problem for the USA poultry industry. Current disposal methods such as land application and feeding to cattle are now under pressure because of pollution of water resources due to leaching, runoffs and concern for mad cow disease contamination of the food chain. Incineration or combustion is potentially applicable to large scale operations, but for small scale growers and EPA non-attainment areas, this is not a suitable option because of the high cost of operation. Thus, there is a need for developing appropriate technologies to dispose poultry litter.Poultry litters from broiler chicken and turkey houses, as well as bedding material were converted into biocrude oil in a fast pyrolysis fluidized bed reactor. The biocrude oil yields were relatively low ranging from 36 wt% to 50 wt% depending on the age and bedding material content of the litter. The bedding material (which was mostly hardwood shavings) biocrude oil yield was 63 wt%. The higher heating value (HHV) of the poultry litter biocrude oils ranged from 26 MJ/kg to 29 MJ/kg while that of the bedding material was 24 MJ/kg. The oils had relatively high nitrogen content ranging from 4 wt% to 8 wt%, very low sulfur (<1 wt%) content and high viscosity. The viscosities of the oils appeared to be a function of both the source of litter and the pyrolysis temperature. The biochar yield ranged from 27 wt% to 40 wt% depending on the source, age and composition of the poultry litter. The biochar ash content ranged from 24 wt% to 54 wt% and was very rich in inorganic components such as potassium and phosphorous.
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