Development, validation, and uncertainty measurement of multi-residue analysis of organochlorine and organophosphorus pesticides using pressurized liquid extraction and dispersive-SPE techniques

Increased water use associated with rapid growth in the Las Vegas Valley has inadvertently led to the creation of unique wetland systems in Southern Nevada with an abundance of biological diversity. Constructed and naturally created wetlands in the Las Vegas Valley watershed were studied to characterize and understand their potential role for improving ecosystem services (i.e., water purification). Nutrient and metal removal was assessed at four sites including a natural urban runoff wetland, a constructed urban runoff wetland, a constructed wastewater wetland, and a natural urban runoff/wastewater wetland. Plant nutrient uptake was dependent on ambient nutrient concentrations in water and sediments of specific wetlands, irrespective of the type of plants present. Phosphorus was mostly concentrated in below-ground plant parts whereas nitrogen was concentrated in above-ground parts. As for metalloids, bulrushes were more efficient than cattails at taking up arsenic and selenium. Averaging all the wetland sites and plant species, total nitrogen, phosphorus, arsenic and selenium removal was 924.2, 61.5, 0.30, and 0.38 kg/ha/year, respectively. Our findings suggest that natural and created wetland systems can improve water quality in the Las Vegas Valley watershed for some common pollutants, however, other measures are still needed to improve water quality below regulatory thresholds.