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用MnSO4-NiSO4取代Ag2SO4协同催化快速测定CODCr
引用本文:朱秀华,王炜.用MnSO4-NiSO4取代Ag2SO4协同催化快速测定CODCr[J].上海环境科学,2002,21(8):501-502,505.
作者姓名:朱秀华  王炜
作者单位:大连铁道学院环境科学与工程系,大连铁道学院环境科学与工程系 大连 116028,大连 116028
摘    要:在标准重铬酸钾法中,提出用MnSO4-NiSO4组合催化剂取代Ag2SO4催化剂,快速测定废水的CODcr。其最佳实验条件为质量之比MnSO4:NiSO4=1:1.5,MnSO4-NiSO4总量为0.15g,加热回流时间为5min。通过对8种不同浓度的标准邻苯二钾酸氢钾样品和5种废水样分析,经统计检验表明,本方法与标准重铬酸钾法无显著性差异,两者具有较好的可比性。

关 键 词:MnSO4-NiSO4  Ag2SO4  协同催化  CODcr  快速测定  催化剂  重铬酸钾法  废水处理

Study on Rapid Determination of CODCr by Using MnSO4-NiSO4 as Catalyst
Zhu Xiuhua Wang Wei.Study on Rapid Determination of CODCr by Using MnSO4-NiSO4 as Catalyst[J].Shanghai Environmental Science,2002,21(8):501-502,505.
Authors:Zhu Xiuhua Wang Wei
Abstract:A method for determination of CODCr in waste-water without Ag2SO4has been proposed. The optimal experimental conditions were as follows: Weight ratio of MnSO4:NiSO4 was 1:1.5, and the total weight was 0.2g, reflux time was 5 minutes. 13 water samples have been analyzed with this method, and compared with the standard potassium dichromate method. The result showed that there were no different between them.
Keywords:COD_(Cr) Rapid determination Catalyst
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