Adsorption of vanadate(V) on Fe(III)/Cr(III) hydroxide waste |
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Authors: | K Prathap C Namasivayam |
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Institution: | (1) Environmental Chemistry Division, Department of Environmental Sciences, Bharathiar University, Coimbatore, 641046, India |
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Abstract: | Adsorption of vanadate(V) from aqueous solution onto industrial solid ‘waste’ Fe(III)/Cr(III) hydroxide was investigated.
HCl treated Fe(III)/Cr(III) hydroxide was found to be more efficient for the removal of vanadate(V) compared to untreated
adsorbent. The adsorption follows second-order kinetics. Langmuir and Freundlich isotherms have been studied. The Langmuir
adsorption capacity (Q
0) of the treated and untreated adsorbents was found to be 11.43 and 4.67 mg g−1, respectively. Thermodynamic parameters showed that the adsorption process was spontaneous and endothermic in the temperature
range 32–60°C. Maximum adsorption was found at system pH 4.0. The adsorption mechanism was predominantly ion exchange. Effect
of other anions such as phosphate, selenite, molybdate, nitrate, chloride, and sulfate on adsorption of vanadium has been
examined. |
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Keywords: | |
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