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非贵金属催化还原水中的硝酸盐氮
引用本文:叶舒帆,胡筱敏,和英滇,张杨.非贵金属催化还原水中的硝酸盐氮[J].环境化学,2011,30(10):1711-1717.
作者姓名:叶舒帆  胡筱敏  和英滇  张杨
作者单位:1. 东北大学资源与土木工程学院,沈阳,110004/温州市环境保护设计科学研究院,温州,325027
2. 东北大学资源与土木工程学院,沈阳,110004
3. 温州医学院信息与工程学院,温州,325035
基金项目:国家科技重大专项课题(20092X07526-006)资助
摘    要:基于双金属催化还原NO3--N的机理分析和常见金属催化电解脱硝技术的初步研究成果,对非贵金属元素催化还原水中NO3--N进行了实验研究.实验数据表明,Fe、Cu、Co、Pb和Zn 5种元素在阴极电场作用下对NO3--N具有较高的催化还原活性;NO3--N催化还原主要产物为NO2--N和NH4+-N,产物比例受催化元素选...

关 键 词:硝酸盐氮  非贵金属  催化还原  电解

STUDY ON NO_3~--N REMOVAL IN WATER BY NON-PRECIOUS METAL CATALYTIC REDUCTION
YE Shufan, HU Xiaomin HE Yingdian ZHANG Yang.STUDY ON NO_3~--N REMOVAL IN WATER BY NON-PRECIOUS METAL CATALYTIC REDUCTION[J].Environmental Chemistry,2011,30(10):1711-1717.
Authors:YE Shufan  HU Xiaomin HE Yingdian ZHANG Yang
Institution:YE Shufan1,2 HU Xiaomin1 HE Yingdian1 ZHANG Yang3 (1.College of Resource and Civil Engineering,Northeastern University,Shenyang,110004,China,2.Wenzhou Environmental Protection Design & Research Institute,Wenzhou,325027,3.Wenzhou Medical College of Information & Engineering,325035,China)
Abstract:In this work,research of NO-3-N catalytic reduction by non-precious metals was carried out,based on the mechanism analysis of bimetallic catalytic reduction on NO-3-N and the research of common metallic catalytic electrolysis denitrification.The results indicate that Fe,Cu,Co,Pb and Zn presented high catalytic reductive activity for NO-3-N in cathode field.The major products of NO-3-N catalytic reduction were NO-2-N and NH+4-N and the proportion of the reduction products was influenced by the catalyst selec...
Keywords:nitrate-N  non-precious metal  catalytic reduction  electrolysis    
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