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水体沉积物中有机质结构特征与毒害有机物的吸附模式研究
引用本文:王伟伟,吴宏海,郭杏妹,邓志芬,曾建敏,曾丁才,林怡英.水体沉积物中有机质结构特征与毒害有机物的吸附模式研究[J].海洋环境科学,2008,27(6).
作者姓名:王伟伟  吴宏海  郭杏妹  邓志芬  曾建敏  曾丁才  林怡英
作者单位:华南师范大学,化学与环境学院,广东,广州,510006
基金项目:国家自然科学基金 , 广东省自然科学基金  
摘    要:以珠江广州河段沉积物为研究对象,利用红外、紫外、荧光、X射线衍射等手段研究了沉积物中有机质的结构,与其他地区相比发现其芳化度和不饱和度较高,含N量也较高.以萘为吸附质,在碱处理前后的沉积物样品做吸附实验,结果发现沉积物样品接近线性吸附,而碱处理过后却呈现明显的非线性吸附,吸附机理的差异显示与其结构有密切的关系.

关 键 词:有机质结构  吸附  高效液相色谱

Study on structure characters and sorption mode of organic sediment in water
WANG Wei-wei,WU Hong-hai,GUO Xing-mei,DENG Zhi-fen,ZENG Jian-min,ZENG Ding-cai,LIN Yi-ying.Study on structure characters and sorption mode of organic sediment in water[J].Marine Environmental Science,2008,27(6).
Authors:WANG Wei-wei  WU Hong-hai  GUO Xing-mei  DENG Zhi-fen  ZENG Jian-min  ZENG Ding-cai  LIN Yi-ying
Institution:WANG Wei-wei,WU Hong-hai,GUO Xing-mei,DENG Zhi-fen,ZENG Jian-min,ZENG Ding-cai,LIN Yi-ying(School of Chemistry , Environment,South China Normal University,Guangzhou 510006,China)
Abstract:The structure characters of organic sediment in water were exposed using FI-IR,UV-Vis,FS,XRD.The result showed that there are more aromatics and unsaturated bonds in the organic matter.The content of nitrogen is higher than other districts.The sorption experiment was carried on in condition of the naphthalene as a sorption matter,and the sediment and residue(that distilled HA) as the adsorbents.Because of the different structure characters,the two samples have the different sorption mechanism.The sorption c...
Keywords:structure of OM  sorption  HPLC  
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