天然和巯基改性沸石吸附水溶液中重金属Hg^2+的特征研究 |
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引用本文: | 张新艳,;王起超,;张少庆,;孙晓静,;张仲胜.天然和巯基改性沸石吸附水溶液中重金属Hg^2+的特征研究[J].环境污染治理技术与设备,2009(3):455-460. |
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作者姓名: | 张新艳 ;王起超 ;张少庆 ;孙晓静 ;张仲胜 |
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作者单位: | [1]中国科学院东北地理与农业生态研究所,长春130012; [2]中国科学院研究生院,北京100049; [3]吉林农业大学资源与环境学院,长春130118 |
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基金项目: | 中国科学院知识创新工程重要方向项目(KZCX3-SW-437) |
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摘 要: | 为了提高沸石对汞的吸附性,利用半胱胺盐酸盐对天然斜发沸石进行改性,制得巯基改性沸石。研究了吸附剂用量、pH值、温度、Hg^2+浓度和吸附时间对沸石和巯基改性沸石吸附Hg^2+的影响,并进一步研究了吸附机理。结果表明,巯基改性沸石吸附Hg^2+受pH值、温度的影响较小,吸附机制主要是沸石表面的硫与Hg^2+的化学反应。而天然沸石对Hg^2+的吸附主要是离子交换作用,受温度、pH值等的影响较大,随温度的升高吸附量下降。整个吸附过程以较快的速度进行。天然沸石在吸附时间为1h、巯基改性沸石在0.5h时基本达到吸附平衡。吸附条件试验和Langmuir等温吸附模型都表明,巯基改性沸石对Hg^2+的吸附能力得到了很大的提高,吸附容量由8.06mg/g提高到19.88mg/g,提高了146.65%。
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关 键 词: | 巯基 改性沸石 天然沸石 Hg2+ 吸附条件 吸附机理 |
Study on characterization of mercury sorption by natural and thiol modified zeolites |
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Institution: | Zhang Xinyan,Wang Qichao, Zhang Shaoqing, Sun Xiaojing,Zhang Zhongsheng(1. Northeast Institute of Geography and Agricultural Ecology, Chinese Academy of Sciences, Changchun 130012 ; 2. Graduate School of Chinese Academy Sciences, Beijing 100049 ; 3. College of Resources and Environments,Jilin Agricultural University,Changchun 130118 ) |
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Abstract: | This work, using cysteamine hydrochloride to modify natural clinoptilolite zeolites, results in great enhancement of absorption capacity. The effects of absorber dosage, pH values, temperature, adsorption time and Hg^2+ concentration on Hg^2+ adsorption and adsorption mechanism are researched. The result shows that the mercury retention by the modified zeolite is attributed to the metal-chelating S functionality, while the one by the natural zeolite is cation exchange. The pH and temperature factors that have slightly effect on the modified zeolite adsorption could significantly affect the natural zeolite; the higher the temperature is, the lower the sorption rate is. Within a high rate of the adsorption process, the modified zeolite takes 0.5 h to reach the adsorption equilibrium, while the natural zeolite takes 1 h. The Langmuir isotherm model and the adsorption conditions experiment both indicate that the modification has greatly enhanced the adsorption capacity for Hg^2+ , the maximum capacity is increased by 146.65% , from 8. 06 mg/g to 19.88 mg/g Hg. |
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Keywords: | thiol group modified zeolite natural zeolite Hg^2 + adsorption condition adsorption mechanism |
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