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金在热液中的地球化学性质实验研究
引用本文:周茂,蔡元吉.金在热液中的地球化学性质实验研究[J].资源调查与环境,1998(3).
作者姓名:周茂  蔡元吉
作者单位:南京地质矿产研究所!南京,210016,南京地质矿产研究所!南京,210016
摘    要:通过近百次实验研究表明,金在水热条件下的地球化学行为具有以下几个特点:金在氧化条件下溶解,还原条件下沉淀;金在高温下溶解,低温下沉淀;金在碱性或酸性溶液中溶解,在中性溶液中沉淀;金在低压下溶解,在高压下沉淀;随着fs八的增加,金的溶解度随之增加;金可以An(HS)4]、Au(HS)2]-、Au(Cl4)]、Au(Cl2)]-等络合物形式存在于热液中;在热液中金普遍以An3+的络合物形式存在,Aul+的络合物形式次之,随着温度的升高,热液中Au1+的含量明显增加。

关 键 词:  热液  地球化学  实验研究

EXPERIMENTAL RESEARCH ON AU'S GEOCHEMICAL PROPERTIES IN HYDROTHERMAL SOLUTIONS
Zhou Mao, Chi Yuanji.EXPERIMENTAL RESEARCH ON AU'S GEOCHEMICAL PROPERTIES IN HYDROTHERMAL SOLUTIONS[J].Resources Survey & Environment,1998(3).
Authors:Zhou Mao  Chi Yuanji
Abstract:The results of nearly a hundred experiments attested that Au, under hydrothermal conditions, displays following geochemical characteristics:It dissolves in oxidation and deposits in reduction;It dissolves under high temperature and deposits under low temperature;It dissolves in alkali or acid solutions and deposits in neutral solutions;It dissolves under low pressure and deposits under high pressure;Its solubility increases as fs2 going up;It can exist in hydrothermal solutions, taking the form of some complex compounds as Au(HS)4] -. Au(HS)2 ] -. Au(Cl4) -. Au(Cl2)] etc;It appears in thermal solutions mostly in the form of Au3 complex compounds, lesser in Aul complex compounds, and Au1 content in thermal solution increases as the temperature going up.
Keywords:Au thermal solution geochemistry experimental research
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