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吸附饱和活性炭的Fenton试剂再生
引用本文:李小豹,杨春平,郭俊元,杨佳,邱国良,易斌.吸附饱和活性炭的Fenton试剂再生[J].环境污染治理技术与设备,2013(10):3867-3873.
作者姓名:李小豹  杨春平  郭俊元  杨佳  邱国良  易斌
作者单位:[1]湖南大学环境科学与工程学院,长沙410082 [2]环境生物与控制教育部重点实验室(湖南大学),长沙410082 [3]浙江省固体废物处理与资源化重点实验室,浙江工商大学环境科学与工程学院,杭州310018
基金项目:国家自然科学基金资助项目(51278464)
摘    要:颗粒活性炭吸附有机废水中二异丙基苯等有机物后,采用Fenton试剂对活性炭进行氧化再生。研究H2O2与Fe2+的摩尔配比及投加量、pH、温度、再生时间等因素对活性炭再生效果的影响。实验结果表明,Fenton体系中Fe2+和H2O2的摩尔比为1:20,H2O2投加量为120mmol/L,pH为3,再生温度为25℃,再生时间为70min时,为最佳再生条件,再生率可达85.6%,且6次连续再生的平均效率仍能达到84.9%。Fenton试剂再生活性炭的方法表现出较高的经济和环境效益。

关 键 词:颗粒活性炭  Fenton试剂  有机废水  再生

Regeneration of saturated activated carbon by Fenton reagent
Li Xiaobao,Yang Chunping,Guo Junyuan,Yang Jia,Qiu Guoliang,Yi Bin.Regeneration of saturated activated carbon by Fenton reagent[J].Techniques and Equipment for Environmental Pollution Control,2013(10):3867-3873.
Authors:Li Xiaobao  Yang Chunping  Guo Junyuan  Yang Jia  Qiu Guoliang  Yi Bin
Institution:1. ColIege of Environmental Science and Engineering, Hunan University, Changsha 410082, China; 2. Key Laboratory of Environmental Biology and Pollution Control (Hunan University) , Ministry of Education, Changsha 410082, China; 3. Zhejiang Provincial Key Laboratory of Solid Waste Treatment and Recycling, College of Environmental Seienee and Engineering, Zhejiang Gongshang University, Hangzhou 310018, China)
Abstract:The regeneration of granular activated carbon (GAC) which adsorbed diisopropyl benzene and other organic matters from organic wastewater using Fenton reagent was investigated at various H2O2 dosages, Fe2+/H2O2 (mole ratio) , pH, temperatures and regeneration times. The optimal operating conditions for the re- generation of GAC were 120 mmol/L H2O2, Fe2+/H2O2 of 1:20, pH of 3, temperature of 25℃ and regeneration time of 70 min. Under these conditions, the regeneration rate achieved its peak of 85.6% and average regenera- tion rate could still achieve 84.9% after six full cycles. Fenton reagent is an economic and environmental way for the regeneration of GAC.
Keywords:granular activated carbon  Fenton reagent  organic wastewater  regeneration
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