Residues and chiral signatures of organochlorine pesticides in sediments from Xiangshan Bay, East China Sea |
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Authors: | Yang Yun H Zhou Shan S Li Yuan Y Xue Bin Liu Teng |
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Institution: | International Joint Research Center for Persistent Toxic Substances, Zhejiang University of Technology, Hangzhou, China. |
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Abstract: | Residual levels and enantiomeric signatures of hexachlorocyclohexanes (HCHs) and dichlorodiphenyltrichloroethanes (DDTs) in surface sediments from Xiangshan Bay, East China Sea were investigated. The concentrations of ∑HCHs (sums of α-, β-, γ-, and δ-HCH) and ∑DDTs (sums of p, p'-DDT, p, p'-DDD,p, p'-DDE, o, p'-DDT, and o, p'-DDD) ranged from 0.14 to 0.67 ng g?1 and 0.61 to 22.38 ng g?1, respectively. A slight potential health risk to the organism was then indicated for the residual levels of DDTs according to the ERL/ERM guidelines. Moreover, the predominant β-HCH implied that the technical HCH contamination was mainly due to the historical usage. But the high ratio of DDT/∑DDTs depicted a cocktail input pattern of fresh and weathered DDTs. The enantiomeric fractions (EFs) of α-HCH, o, p'-DDT, and o, p'-DDD were also determined. The degradation of α-HCH was enantioselective in all sediments samples, resulting in an enrichment of (-)-enantiomers. However, the racemic residues of o, p'-DDT and o, p'-DDD were observed in all sediments samples. |
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