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稠油乳化段废水厌氧处理过程中COD与BOD5的协同变化及可生化性研究
引用本文:郭书海,张海荣,曲久辉,刘会娟.稠油乳化段废水厌氧处理过程中COD与BOD5的协同变化及可生化性研究[J].环境科学学报,2002,22(1):29-33.
作者姓名:郭书海  张海荣  曲久辉  刘会娟
作者单位:1. 中国科学院生态环境研究中心环境水化学国家重点实验室,北京,100085
2. 中国科学院沈阳应用生态研究所,沈阳,110016
基金项目:中国科学院知识创新工程项目 (KZCX2 40 9)
摘    要:稠油乳化段废水中的主要污染物为有机聚合物和石油类污染物,BOD5/COD值极低,可生化性差,通过厌氧处理可使污染物发生水解反应,BOD5/COD值由0.08升为0.15(288h),与其它难降解有机废水的厌处理结果不同,在BOD5增加的同时,COD亦大幅度增加,而在全部厌氧反应过程中,TOC一直呈下降趋势,表明水样中的污染物在生物作用下不断得到消减;在COD达到最高时,石油类污染物中胶质的浓度大幅度降低,烷烃的浓度升高,说明以胶质为代表的大分子污染物因子解反应,由K2Cr2O7不能氧化状态变为可氧化状态,导致COD测量值显著升高。

关 键 词:稠油  采油废水  厌氧处理  COD  BOD5  可生化性  乳化段  废水处理  协同变化
文章编号:0253-2468(2002)-01-0029-05
收稿时间:2/8/2001 12:00:00 AM
修稿时间:2001年2月8日

Study on the behavior of COD vs BOD5 and biodegradability in treatment of anaerobic process for emulsified viscous oil production wastewater
GUO Shuhai,ZHANG Hairong,QU Jiuhui and LIU Huijuan.Study on the behavior of COD vs BOD5 and biodegradability in treatment of anaerobic process for emulsified viscous oil production wastewater[J].Acta Scientiae Circumstantiae,2002,22(1):29-33.
Authors:GUO Shuhai  ZHANG Hairong  QU Jiuhui and LIU Huijuan
Institution:State Key Laboratory of Environmental Aquatic Chemistry,Research Center for Eco Environmental Science,Chinese Academy of Sciences,Beijing 100085,Institute of Applied Ecology,Chinese Academy of Sciences,Shenyang 110016,State Key Laboratory of Environmental Aquatic Chemistry,Research Center for Eco Environmental Science,Chinese Academy of Sciences,Beijing 100085 and State Key Laboratory of Environmental Aquatic Chemistry,Research Center for Eco Environmental Science,Chinese Academy of Sciences,Beijing 100085
Abstract:The main pollutants of viscous oil production wastewater in emulsification stage were organic polymer and petroleum. The COD was higher whereas BOD 5 lower. The value of BOD 5/COD was only 0 08. Through anaerobic pretreatment, the ratio of BOD 5 and COD increased to 0 15 (288h). The abnormal result was that with the increase of BOD 5, the concentration of COD (144h) reachedup to 534mg/L from 324mg/L. TOC decreased gradually in the whole process, with meamt that polymer and petroleum, especially resin, degraded to small molecule and could be oxidized by K 2Cr 2O 7 after anaerobic process. The results in this paper have been applied to the design of a produced water treatment plant.
Keywords:viscous oil wastewater  anaerobic treatment  biodegradability  COD  BOD  5
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