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Zn-TiO_2纳米管的光催化活性
引用本文:梁鸿昌,欧宇达,丘文杰,张国文,李鑫,徐悦华.Zn-TiO_2纳米管的光催化活性[J].生态环境,2011,20(2):323-326.
作者姓名:梁鸿昌  欧宇达  丘文杰  张国文  李鑫  徐悦华
作者单位:华南农业大学理学院生物材料研究所,广东广州,510642
基金项目:广东省科技计划项,华南农业大学"211工程"三期重点建设项目
摘    要:采用水热合成-浸渍法制备锌掺杂TiO2纳米管(Zn-TiO2纳米管),透射电镜照片显示Zn-TiO2纳米管为两端开口形貌均一的中空管状结构,管径约6~8 nm,壁厚约1 nm,长度约50~200 nm。研究了Zn-TiO2纳米管对甲基橙的光催化性能,结果表明:掺杂适量锌提高了TiO2纳米管对甲基橙的光催化降解性能,0.4%Zn-TiO2纳米管的光催化性能最佳。同时还探讨了Zn-TiO2纳米管用量和初始pH值等因素对光催化降解甲基橙的影响,结果显示Zn-TiO2纳米管能有效地降解甲基橙。随着光催化反应进行,CODCr去除率和脱色率变化规律不完全相同,可能是由于芳基和烷基降解速率不同所致。

关 键 词:TiO2纳米管  锌掺杂  水热合成法  甲基橙  CODCr去除率

Study on photocatalytic activity of Zn-TiO2 nanotubes
LIANG Hongchang,OU Yuda,QU Wenjie,ZHANG Guowen,LI Xin,XU Yuehua.Study on photocatalytic activity of Zn-TiO2 nanotubes[J].Ecology and Environmnet,2011,20(2):323-326.
Authors:LIANG Hongchang  OU Yuda  QU Wenjie  ZHANG Guowen  LI Xin  XU Yuehua
Institution:LIANG Hongchang,OU Yuda,QIU Wenjie,ZHANG Guowen,LI Xin,XU Yuehua Institute of Biomaterial,College of Science,South China Agricultural University,Guangzhou 510642,China
Abstract:Zinc-doped titania nanotubes(Zn-TiO2 nanotubes) were synthesized using hydrothermal treatment-impregnation method,and photos of transmission electron microscopy(TEM) show that Zn-TiO2 nanotubes were hollow and open-ended,and they were measured to be about 6 to 8 nm in diameter,with about 1 nm wall thickness,and the lengths in the range of 50 to 200 nm.The photocatalytic activities of Zn-TiO2 nanotubes for the degradation of methyl orange were investigated.The results showed that the photocatalytic activitie...
Keywords:titania nanotubes  zinc-doped  hydrothermal method  methyl orange  CODCr removal efficiency  
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