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硫自养反硝化去除地下水中硝酸盐氮的研究
引用本文:万东锦,刘会娟,雷鹏举,刘锐平,曲久辉.硫自养反硝化去除地下水中硝酸盐氮的研究[J].环境工程学报,2009,3(1):1-5.
作者姓名:万东锦  刘会娟  雷鹏举  刘锐平  曲久辉
作者单位:1. 中国科学院生态环境研究中心环境水质学国家重点实验室,北京,100085;中国科学院研究生院,北京,100049
2. 中国科学院生态环境研究中心环境水质学国家重点实验室,北京,100085
基金项目:国家“863”高技术研究发展计划项目(2006AA06Z302)
摘    要:研究实际地下水硫自养反硝化动力学过程,考察季节因素(温度)对动力学的影响,实验结果表明,地下水升流式硫自养滤柱反硝化动力学符合1/2级动力学模型,其反应速率常数受温度的影响很大,用阿仑尼乌斯方程计算硫自养反硝化活化能为80.38 kJ/mol。硫自养反硝化产生的硫酸根与反硝化掉的硝酸根离子呈线性相关。在地下水不经任何预处理的条件下,硫自养反硝化仍能有效地脱除地下水中的硝酸盐,反应器出水的pH值仍维持在中性范围。

关 键 词:硫自养  反硝化  温度  动力学

Study on the sulfur autotrophic denitrification of groundwater
Wan Dongjin,Liu Huijuan,Lei Pengju,Liu Ruiping and Qu Jiuhui.Study on the sulfur autotrophic denitrification of groundwater[J].Techniques and Equipment for Environmental Pollution Control,2009,3(1):1-5.
Authors:Wan Dongjin  Liu Huijuan  Lei Pengju  Liu Ruiping and Qu Jiuhui
Institution:1. State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085;2. Graduate University of Chinese Academy of Sciences, Beijing 100049,1. State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085,1. State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085,1. State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085 and 1. State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085
Abstract:The kinetics process and temperature impact of natural groundwater denitrified by sulfur autotrophic was investigated. The results revealed that the denitrification rate of up-flow sulfur autotrophic denitrification filter followed a half-order kinetics model; and the reaction rate constant was mainly affected by the temperature. Based on the Arrhenius calculation, the activated energy was 80.38 kJ/mol. The concentration of generated sulfate during this denitrification process was linearly related to the concentration of reduced nitrate. Without any pretreatment process, the reactor could remove nitrate efficiently from groundwater, and the pH of effluent kept neutralization.
Keywords:sulfur autotrophic  denitrification  temperature  kinetics
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