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THE TENDENCY OF A NEW WATER DISINFECTANT TO PRODUCE TOXIC TRIHALOMETHANES1
Authors:S D Worley  H D Burkett  J F Price
Institution:1. Respectively, Professor and Graduate Student, Department of Chemistry, 208 Saunders Hall, Auburn University, Auburn, Alabama 36849;2. and Chemist, Alabama Department of Environmental Management Laboratory, Montgomery, Alabama 36130.
Abstract:A new organic N-chloramine disinfectant (3-chloro-4, 4-dimethyl-2-oxazolidinone, agent I) has been compared with calcium hypochlorite as to its tendency to react with organic matter in water to produce toxic trihalomethanes. Agent I reacts much less readily with organic demand than does calcium hypochlorite. This study shows that agent I should be safe to use as a disinfectant for water containing appreciable organic load in either sunlight or darkness. On the other hand, calcium hypochlorite may not be a satisfactory disinfectant from the toxicity standpoint for water which contains organic load which must be stored for extended time periods in either sunlight or darkness.
Keywords:bactericidal agent  disinfection  water treatment  water purification  N-chloramines  trihalomethanes  chloroform
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