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5083铝合金电化学性能影响因素研究
引用本文:陈珊,李国明,常万顺,陈学群.5083铝合金电化学性能影响因素研究[J].装备环境工程,2013,10(1):22-25.
作者姓名:陈珊  李国明  常万顺  陈学群
作者单位:1. 海军工程大学,武汉,430033
2. 海军工程大学,武汉430033;武汉理工大学华夏学院,武汉430022
基金项目:海军工程大学基金项目(20100604000009)
摘    要:采用动电位扫描及循环伏安试验方法,研究了工作电极表面状态、Cl浓度、pH值等因素对5083铝合金在质量分数为3.5%的NaCl溶液中电化学性能的影响。研究结果表明,试样表面进行抛光后,点蚀电位变正,点蚀保护电位正移。随着Cl-浓度的降低,点蚀电位磊明显正移;当Cl-浓度超过1%(质量分数)后,Cl-浓度对鼠的影响则不明显。溶液的pH值及其它阴离子的添加均会对5083铝合金点蚀电位及保护电位产生影响。

关 键 词:5083铝合金  点蚀  动电位和循环极化  表面状态  pH值
收稿时间:2012/8/24 0:00:00
修稿时间:1/1/2013 12:00:00 AM

Research of Influential Factors on Electrochemical Behavior of AA5083
CHEN Shan,LI Guo-ming,CHANG Wan-shun and CHEN Xue-qun.Research of Influential Factors on Electrochemical Behavior of AA5083[J].Equipment Environmental Engineering,2013,10(1):22-25.
Authors:CHEN Shan  LI Guo-ming  CHANG Wan-shun and CHEN Xue-qun
Institution:1(1.Navy Engineering University,Wuhan 430033,China; 2.School of Huaxia,Wuhan University of Technology,Wuhan 430022,China)
Abstract:The influential factors such as surface state of working electrode, the chloride concentration, and pH value on AA5083 electrochemical behavior in 3.5% NaC1 solution were investigated using potentiodynamic polarization and cyclic polarization experiment. The results showed that the Epit and Ecor potentials shift to positive values when specimen surface is polished; E6 shift to positive significantly with decrease of chloride concentration; chloride concentration has little influence on EB when the concentration exceeds 1.0%; pH and other ion concentration has influence on Epit and Ep.
Keywords:AA5083  pitting corrosion  potentiodynamic and cyclic polarization  surface state  pH value
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