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多氯联苯光化学降解研究的最新进展
引用本文:李俊生,王兴戬. 多氯联苯光化学降解研究的最新进展[J]. 四川环境, 2010, 29(3): 77-81
作者姓名:李俊生  王兴戬
作者单位:哈尔滨商业大学环境工程系,哈尔滨,150076;中国市政工程华北设计研究总院,天津,300074
基金项目:黑龙江省自然科学基金,黑龙江省教育厅科技研究项目 
摘    要:综述了近10年以来多氯联苯(PCBs)在有机相、表面活性剂中的直接光化学降解行为,以及PCBs在水相中的光敏化反应和光催化反应等间接光化学降解行为。从光解动力学、光解途径、光解机理以及光解产物等几方面阐述了PCBs的光化学行为,光催化降解有机污染物是一种很有发展前景的有机污染物治理技术。

关 键 词:多氯联苯  光化学降解  表面活性剂  光敏剂  光催化

Latest Advances in Photochemical Degradation of Polychlorinated Biphenyls
LI Jun-sheng,WANG Xing-jian. Latest Advances in Photochemical Degradation of Polychlorinated Biphenyls[J]. Sichuan Environment, 2010, 29(3): 77-81
Authors:LI Jun-sheng  WANG Xing-jian
Affiliation:1.Department of Environmental Engineering,Harbin University of Commerce,Harbin 150076,China; 2.North China Municipal Engineering Design & Research Institute,Tianjin 300074,China)
Abstract:The advances in recent ten years in the fields of direct photochemical degradation of polychlorinated biphenyls(PCBs) in organic solvents and surfactant as well as indirect photochemical degradation in water including photosensitized reaction and light-catalyzed reaction are reviewed.The photochemical reaction of PCBs is discussed in the respects of photolytic kinetics,pathway,mechanism and products.Photocatalytic degradation of organic pollutants is a promising treatment technology.
Keywords:Polychlorinated biphenyls  photochemical degradation  surfactant  photosensitizer  photocatalysis
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