Sensitivity of air quality model prediction to parameterization of vertical eddy diffusivity |
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Authors: | Zhiwei Han Meigen Zhang Junling An |
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Institution: | (1) Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China |
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Abstract: | This paper investigates the effects of vertical eddy diffusivities derived from the 3 different planetary boundary layer (PBL)
schemes on predictions of chemical components in the troposphere of East Asia. Three PBL schemes were incorporated into a
regional air quality model (RAQM) to represent vertical mixing process and sensitivity simulations were conducted with the
three schemes while other options are identical. At altitudes <2km, all schemes exhibit similar skill for predicting SO2 and O3, but more difference in the predicted NOx concentration. The Gayno–Seaman scheme produces the smallest vertical eddy diffusivity (Kz) among all schemes, leading to
higher SO2 and NOx concentrations near the surface than that from the other 2 schemes. However, the effect of vertical mixing on O3 concentration is complex and varies spatially due to chemistry. The Gayno–Seaman scheme predicts lower O3 concentrations than the other two schemes in the parts of northern China (generally VOC-limited) and higher ones in most
parts of southern China (NOx-limited). The Byun and Dennis scheme produces the largest mixing depth in the daytime, which bring more NOx into upper levels, and the mixing depth predicted by the Gayno–Seaman scheme is the smallest, leading to higher NOx and lower O3 concentrations near the surface over intensive emission regions. |
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Keywords: | Vertical mixing Planetary boundary layer Air quality model Chemistry Sensitivity simulation TRACE-P |
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