| 改性ACF－PAN吸附SO_2前后表面结构变化及机机理究 |
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| 引用本文： | 刘中正,串亚权,罗德明,尹华强,刘谦,华坚,胡玉英.改性ACF－PAN吸附SO_2前后表面结构变化及机机理究[J].中国环境科学,1994(6). |
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| 作者姓名： | 刘中正 串亚权 罗德明 尹华强 刘谦 华坚 胡玉英 |
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| 作者单位： | 成都科技大学环境系 |
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| 摘 要： | 以自制ＰＡＮ－基聚丙烯腈活性碳纤维ＡＣＦ－ＰＡＮ（ＡＣＦ－活性碳纤维、ＰＡＮ－聚丙烯腈）和改性处理的ＡＣＦ－ＰＡＮ吸附ＳＯ_２，借助ＩＲ、ｘ－光电子能谱分析等研究ＡＣＦ－ＰＡＮ改性处理及吸附ＳＯ_２前后表面结构变化。结果表明：各型ＡＣＦ－ＰＡＮ吸附ＳＯ_２的活性中心为表面结构中的含氮官能团以及引入的金属氧化物，其吸附机理是活性氮催化或电子传递。
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| 关 键 词： | 活性碳纤维 改性 表面结构 吸附SO_2机理 |
CHANGE OF SURFACE STRUCTURE BEFORE AND AFTER SO_2 ADSORPTION ON MODIFIED ACF-PAN AND ITS MECHANISM |
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| Liu Zhongzheng ,Cuan Yaqnan, Luo Deming,Yin Huaqiang,Liu Qian, Hua Jian, Hu Yuying.CHANGE OF SURFACE STRUCTURE BEFORE AND AFTER SO_2 ADSORPTION ON MODIFIED ACF-PAN AND ITS MECHANISM[J].China Environmental Science,1994(6). |
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| Authors: | Liu Zhongzheng Cuan Yaqnan Luo Deming Yin Huaqiang Liu Qian Hua Jian Hu Yuying |
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| Abstract: | The mechanism of ACF-PAN and modified ACFPAN adsorbing SO2 and its activated center are studied in this paper, as well as the change of surface structure before and after SO2 adsorption, by IP and X-ray photoelectron spetrometry.The results indicate that the activated center on modified ACFPAN and ACF-PAN prepared consists of functional group containing nitrogen and metal oxide. The adsorption mechanism of SO2 on ACF-PAN and modified ACF-PAN is the catalysis by activated nitrogen or electron transport. |
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| Keywords: | Active carbon fiberi Modify Surface structure Mechanism ofSO_2 adsorption |
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